{"id":"W7019313653","doi":"","title":"Experimental and computational studies of hydroxyl radical
\\nkinetics at very low temperatures","year":2012,"lang":"en","type":"dissertation","venue":"White Rose eTheses Online (University of Leeds, The University of Sheffield, University of York)","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Quantum tunnelling; Hydrogen atom abstraction; Radical; Hydrogen; Limiting; Quantum; Methanol; Activation energy; Hydroxyl radical; Quantum chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000108913,0.0003721882,0.0009682889,0.0001938028,0.0005612509,0.000003736133,0.000744908,0.0002328528,0.0003132899],"category_scores_gemma":[0.00001204362,0.0004450859,0.0004215451,0.0002704292,0.001966635,0.0002300091,0.0006378915,0.0004892179,0.000002894866],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001027043,"about_ca_system_score_gemma":0.0001076569,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001232504,"about_ca_topic_score_gemma":0.0004759172,"domain_scores_codex":[0.9985512,0.000105599,0.0002254141,0.0003878775,0.0004502817,0.0002795534],"domain_scores_gemma":[0.9977754,0.0004797614,0.0008473833,0.0003500165,0.0004297929,0.0001176336],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"qualitative","study_design_gemma":"qualitative","study_design_scores_codex":[0.01464937,0.01092655,0.0558638,0.007511871,0.02153816,0.0001153351,0.6072826,0.03650918,0.1993291,0.01450459,0.01916458,0.01260479],"study_design_scores_gemma":[0.006297582,0.0007077326,0.0252043,0.002045413,0.002736236,0.000004027348,0.937138,0.0008483613,0.01504248,0.003489902,0.004987503,0.001498504],"study_design_candidate":"qualitative","study_design_consensus":"qualitative","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9939557,0.001738744,0.0004913177,0.0002401846,0.0001125683,0.0002776397,0.0005935792,0.00002180009,0.002568522],"genre_scores_gemma":[0.9921449,0.000421155,0.00222401,0.000006376038,0.00005368219,1.602859e-8,0.0005639758,0.00001957398,0.004566258],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3298553,"threshold_uncertainty_score":0.9998001,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01361560157153658,"score_gpt":0.2341293006017321,"score_spread":0.2205136990301956,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}