{"id":"W7024080090","doi":"","title":"A regioselective approach to trisubstituted 2 (or 6)-arylaminopyrimidine-5-carbaldehydes and their application in the synthesis of structurally and electronically unique G boolean AND C base precursors","year":2008,"lang":"en","type":"article","venue":"NPARC","topic":"Synthesis of heterocyclic compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Regioselectivity; Base (topology); Boolean function; Substitution (logic); Key (lock)","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002439361,0.0002374341,0.000356927,0.0001014971,0.0001098116,0.00002700122,0.0002728667,0.000119478,0.000009689051],"category_scores_gemma":[0.0003268715,0.0001578504,0.00003684821,0.0001946454,0.0002449278,0.00009786853,0.0000753309,0.0002099449,1.982615e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005659541,"about_ca_system_score_gemma":0.00006465168,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006512132,"about_ca_topic_score_gemma":0.00009181592,"domain_scores_codex":[0.998713,0.00009780481,0.0002980338,0.0004610489,0.0001633097,0.0002668152],"domain_scores_gemma":[0.9984595,0.0009058132,0.0001182998,0.0003867858,0.00004426518,0.00008536892],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009870862,0.0002398786,0.00577926,0.0002603244,0.0001192366,0.00000771268,0.005845777,0.000009023244,0.9383149,0.001980687,0.0001483411,0.04630784],"study_design_scores_gemma":[0.001506529,0.0002288208,0.04692565,0.0001970556,0.0001140069,0.0008976156,0.00225698,0.005106123,0.9331442,0.008255349,0.0006083389,0.0007593256],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.991837,0.0002205947,0.0002445375,0.0004229461,0.000003258378,0.0003619522,0.00001400189,0.00003791039,0.006857832],"genre_scores_gemma":[0.9964525,0.0002506766,0.002944332,0.00006154905,0.00002883109,0.00021239,0.000004331638,0.00002149863,0.00002388498],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04554851,"threshold_uncertainty_score":0.6436952,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01572300286161717,"score_gpt":0.2217893410827405,"score_spread":0.2060663382211234,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}