{"id":"W7024310383","doi":"","title":"The sequential insertion of carbon monoxide and imines into nickel-carbon sigma-bonds and kinetic analysis of imine insertion into palladium-acyl sigma-bonds","year":2007,"lang":"en","type":"dissertation","venue":"eScholarship@McGill (McGill)","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; McGill University","keywords":"Imine; Carbon monoxide; Migratory insertion; Insertion reaction; Electrophile; Steric effects","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001453245,0.0001812251,0.0001423528,0.0002076842,0.00009259907,0.0003031615,0.0001771279,0.0001355462,0.001257912],"category_scores_gemma":[0.0002334958,0.0001443724,0.0001086847,0.0001553351,0.0001097668,0.0003607759,0.0001098888,0.0002973452,0.0003789268],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002635105,"about_ca_system_score_gemma":0.0001271872,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006421917,"about_ca_topic_score_gemma":0.0007146172,"domain_scores_codex":[0.9998888,0.00001192635,0.000006797802,0.00002692011,0.00004091148,0.00002471878],"domain_scores_gemma":[0.9999022,0.0000333325,0.00002650573,0.000007682568,0.00001928109,0.00001099118],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001674853,0.00003857521,0.000854331,0.00006472182,0.00001041253,0.00006752054,0.00008318836,0.00111003,0.9932219,0.0006403991,0.0001033314,0.003638059],"study_design_scores_gemma":[0.000003768788,0.0001482881,0.001120624,0.000003352299,0.000005079969,0.00002364482,0.00002539723,0.003701726,0.9942879,0.00003937079,0.0006347195,0.000006070019],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942503,0.0004983355,0.002973283,0.00002055151,0.000005609052,0.0000179683,0.0001967829,0.00004971002,0.001987475],"genre_scores_gemma":[0.9956536,0.0004494145,0.001641708,0.000005861554,0.000001926671,0.00001668063,0.0002322043,0.00001068416,0.001987959],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001257912,"threshold_uncertainty_score":0.004208207,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01174423200786743,"score_gpt":0.2552554517201678,"score_spread":0.2435112197123004,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}