{"id":"W7024775707","doi":"","title":"Synthesis of Cyclic Î±,Î²-unsaturated Ketones via a Divergent Aldehyde Allylation and Ring-closing Metathesis Method","year":2011,"lang":"en","type":"dissertation","venue":"Library and Archives Canada (Government of Canada)","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Enone; Aldehyde; Isomerization; Ketone; Metathesis; Ring-closing metathesis; Alcohol; Acyclic diene metathesis; Allyl alcohol","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00004641418,0.0004629397,0.0007739333,0.00004242908,0.0001457689,0.00001971344,0.0003139511,0.000165711,0.0004474959],"category_scores_gemma":[0.00006177155,0.0004706933,0.00008600936,0.00009681029,0.00007579984,0.0001729612,0.0001175379,0.0002545457,2.709244e-9],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000169272,"about_ca_system_score_gemma":0.0009321606,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004795152,"about_ca_topic_score_gemma":0.006576828,"domain_scores_codex":[0.9969574,0.0001261134,0.0006823069,0.0005295211,0.001382021,0.0003226512],"domain_scores_gemma":[0.9973428,0.001202106,0.0007981698,0.000390333,0.000002960079,0.0002636846],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006014465,0.00004490772,0.001324755,0.002135255,0.0005907297,0.00002703645,0.0003089372,0.000006577982,0.9500625,0.0007575044,0.00003157915,0.04410878],"study_design_scores_gemma":[0.0001910115,0.00001171382,0.006145808,0.0005908154,0.0004446614,0.00001236242,0.002248756,0.0007842803,0.9876418,0.0005658855,0.0009346957,0.0004282342],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6739128,0.002343243,0.0005034052,0.0003962019,0.0003999274,0.0002941009,0.0008303895,0.0000490459,0.3212709],"genre_scores_gemma":[0.9707363,0.0006290955,0.01723604,0.0000561961,0.00007166374,0.00002437988,0.0000930787,0.00009722516,0.01105597],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.310215,"threshold_uncertainty_score":0.9997745,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005864194011073042,"score_gpt":0.1842046971357364,"score_spread":0.1783405031246634,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}