{"id":"W7045757093","doi":"","title":"Br??nsted acid-catalyzed reaction of alkynyltrifluoroborates with acetals and ketals","year":2015,"lang":"en","type":"dissertation","venue":"e-scholar@UOIT (University of Ontario Institute of Technology)","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ontario Tech University","funders":"","keywords":"Phenylacetylene; Nucleophile; Catalysis; Functional group; Organic synthesis; Organic molecules","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity"],"consensus_categories":[],"category_scores_codex":[0.0003013677,0.0004749754,0.001162156,0.0008065216,0.0003084193,0.00002920797,0.0007647158,0.001409827,0.0001969657],"category_scores_gemma":[0.0002058934,0.0005707715,0.0002031741,0.0008192361,0.0006839812,0.001087117,0.0001760824,0.001567413,0.00001375628],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008189181,"about_ca_system_score_gemma":0.001787339,"about_ca_topic_candidate":true,"about_ca_topic_consensus":true,"about_ca_topic_score_codex":0.02238839,"about_ca_topic_score_gemma":0.08201986,"domain_scores_codex":[0.9979681,8.618404e-7,0.00051337,0.0007006002,0.000504967,0.0003120927],"domain_scores_gemma":[0.9959575,0.000005629096,0.001814392,0.001032982,0.001057026,0.0001324496],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009213379,0.0002987189,0.0005991862,0.000709055,0.0008870512,0.00005643792,0.001706554,0.00001501691,0.9749358,0.0001780062,0.0001466518,0.01954619],"study_design_scores_gemma":[0.003387158,0.0001718793,0.004037622,0.001207398,0.001435856,0.0001263886,0.006470668,0.000009544955,0.8253194,0.0003386227,0.156782,0.000713499],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942362,0.0005938942,0.000006226884,0.00005511742,0.0002369847,0.0002877333,0.0002579339,0.0001767009,0.004149247],"genre_scores_gemma":[0.968634,0.0002172528,0.01831428,0.0000022182,0.00002621654,0.000004132468,0.003762022,0.00006950748,0.008970328],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1566353,"threshold_uncertainty_score":0.9998866,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01257685796607824,"score_gpt":0.2297587079683137,"score_spread":0.2171818500022354,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}