{"id":"W7071369453","doi":"","title":"Syntheses, Molecular Structures, and Vibrational Spectra of Chloropentacarbonylrhodium(III) and -iridium(III) Undecafluorodiantimonate(V), [Rh(CO)&lt;sub&gt;5&lt;/sub&gt;Cl][Sb&lt;sub&gt;2&lt;/sub&gt;F&lt;sub&gt;11&lt;/sub&gt;]&lt;sub&gt;2&lt;/sub&gt; and [Ir(CO)&lt;sub&gt;5&lt;/sub&gt;Cl][Sb&lt;sub&gt;2&lt;/sub&gt;F&lt;sub&gt;11&lt;/sub&gt;]&lt;sub&gt;2&lt;/sub&gt;:  An Experimental and Density Functional Study","year":2000,"lang":"en","type":"article","venue":"Max Planck Digital Library","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Isostructural; Group (periodic table); Dihedral angle; Bond length; Infrared spectroscopy; Crystal (programming language); Single crystal; Spectral line; Single bond","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","metaepi_broad","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"category_scores_codex":[0.008556553,0.02588364,0.02278506,0.01052879,0.01191791,0.01640004,0.01675821,0.01594828,0.004914285],"category_scores_gemma":[0.002623861,0.02787382,0.009264231,0.01414401,0.01316293,0.02460934,0.01387759,0.01590014,0.003510181],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.007863129,"about_ca_system_score_gemma":0.009119737,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004336269,"about_ca_topic_score_gemma":0.002864934,"domain_scores_codex":[0.9017358,0.005866488,0.02256245,0.02656608,0.02132896,0.02194022],"domain_scores_gemma":[0.9420672,0.007106436,0.01320548,0.01740208,0.00501609,0.01520273],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.01871834,0.01504396,0.008606375,0.00447119,0.0116504,0.01177352,0.003876981,0.00204598,0.8164693,0.009245221,0.08639987,0.01169882],"study_design_scores_gemma":[0.04425024,0.008068374,0.02267113,0.005829393,0.008910424,0.01246824,0.002053226,0.00816921,0.74645,0.006371097,0.1012968,0.03346182],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8607186,0.05267981,0.0007435645,0.002473525,0.01036957,0.01651593,0.02331592,0.008034321,0.02514875],"genre_scores_gemma":[0.9124684,0.0270693,0.002169887,0.003552319,0.01252013,0.003506156,0.02713226,0.007938037,0.00364353],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0700193,"threshold_uncertainty_score":0.9972657,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007620245771223164,"score_gpt":0.1936378094421257,"score_spread":0.1860175636709025,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}