{"id":"W7071369453","doi":"","title":"Syntheses, Molecular Structures, and Vibrational Spectra of Chloropentacarbonylrhodium(III) and -iridium(III) Undecafluorodiantimonate(V), [Rh(CO)<sub>5</sub>Cl][Sb<sub>2</sub>F<sub>11</sub>]<sub>2</sub> and [Ir(CO)<sub>5</sub>Cl][Sb<sub>2</sub>F<sub>11</sub>]<sub>2</sub>:  An Experimental and Density Functional Study","year":2000,"lang":"en","type":"article","venue":"Max Planck Digital Library","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Isostructural; Group (periodic table); Dihedral angle; Bond length; Infrared spectroscopy; Crystal (programming language); Single crystal; Spectral line; Single bond","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001228917,0.0002171613,0.0001575854,0.0001180688,0.0002069929,0.0001468894,0.000515251,0.0001837206,0.00251849],"category_scores_gemma":[0.0001274713,0.0001283692,0.0001515704,0.0001584912,0.0001876907,0.0001849213,0.0001769615,0.0003634558,0.0003476266],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003963214,"about_ca_system_score_gemma":0.0002585704,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001879411,"about_ca_topic_score_gemma":0.002843161,"domain_scores_codex":[0.9999468,0.000005798282,0.000002197705,0.00001025669,0.00001655636,0.00001833987],"domain_scores_gemma":[0.9999683,0.000005136104,0.00000981755,0.000005450372,0.000005910334,0.000005380425],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002821986,0.00005852381,0.0003522413,0.0003072101,0.00001912791,0.0001199046,0.0001764228,0.002490251,0.9830992,0.005406684,0.0006047869,0.007083442],"study_design_scores_gemma":[0.00005576832,0.0005158811,0.001836613,0.00001692581,0.0000234571,0.0001629835,0.0001276075,0.005901191,0.9847277,0.0002529509,0.006343229,0.00003556698],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9898246,0.0006683753,0.003635631,0.00007663753,0.00001860013,0.00002956407,0.0003502213,0.0000574385,0.005338999],"genre_scores_gemma":[0.9947287,0.0006190206,0.002336881,0.00002759449,0.000003856286,0.00003519709,0.0005454131,0.0000187526,0.001684482],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00251849,"threshold_uncertainty_score":0.008425236,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007620245771223164,"score_gpt":0.1936378094421257,"score_spread":0.1860175636709025,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}