{"id":"W7101411836","doi":"10.1016/j.jqsrt.2025.109707","title":"First high-resolution spectral study of the far infrared fundamental OH- torsional band of ethyl alcohol (CH3CH2OH), using synchrotron radiation","year":2025,"lang":"en","type":"article","venue":"Journal of Quantitative Spectroscopy and Radiative Transfer","topic":"Spectroscopy and Laser Applications","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research; Government of Saskatchewan; Canada Foundation for Innovation; University of Saskatchewan","keywords":"Far infrared; Excited state; Synchrotron radiation; Infrared; Fourier transform; Fourier transform spectroscopy; Spectroscopy; Spectrometer","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001783936,0.0002192917,0.0002251575,0.0002553122,0.0003560793,0.0001948726,0.000536087,0.0003262587,0.001046096],"category_scores_gemma":[0.0001963075,0.0001514801,0.0001937452,0.0002672735,0.0004342054,0.0003539187,0.0002529067,0.0006155148,0.0001631362],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001385023,"about_ca_system_score_gemma":0.0001216473,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007339144,"about_ca_topic_score_gemma":0.0009963637,"domain_scores_codex":[0.9999242,0.000009596043,0.000002510763,0.00002086947,0.00002396115,0.00001893712],"domain_scores_gemma":[0.9998522,0.00006085161,0.00002503156,0.00002046567,0.00002606952,0.00001535128],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001541033,0.00002719484,0.0005152275,0.00009446579,0.000007895484,0.00005495846,0.00006454528,0.00007172789,0.9954351,0.0001471379,0.0001950737,0.003232445],"study_design_scores_gemma":[0.00001798001,0.0001953444,0.01411488,0.000009800438,0.00002007225,0.0002245985,0.0001591773,0.001037155,0.9806896,0.0001139046,0.003405893,0.00001153596],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.976468,0.003692798,0.0142662,0.0002307147,0.00005886291,0.00003896044,0.0004129667,0.0001734736,0.004657994],"genre_scores_gemma":[0.9895969,0.0008919758,0.006924171,0.00009433121,0.0000221431,0.00002348569,0.0004258275,0.00002736091,0.001993767],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001046096,"threshold_uncertainty_score":0.003499508,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02153948532882802,"score_gpt":0.3149394285970793,"score_spread":0.2933999432682513,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}