{"id":"W7111418122","doi":"10.1021/acs.jpca.5c03008.s001","title":"Experimental andTheoretical Study of the Kineticsof Dimerization of Ammonia at Low Temperatures","year":2025,"lang":"","type":"article","venue":"Figshare","topic":"Gas Dynamics and Kinetic Theory","field":"Mathematics","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Molecule; Kinetics; Excited state; Helium; Photodissociation; Supersonic speed; Fluorescence; Ammonia; Kinetic energy","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002049936,0.0002268497,0.0002121259,0.00007297017,0.0003714194,0.000172883,0.0003133415,0.0002549806,0.002278047],"category_scores_gemma":[0.0003604495,0.0001174717,0.0001919184,0.0001103113,0.0003582991,0.0002882627,0.0001684617,0.0005331666,0.0003544869],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000744886,"about_ca_system_score_gemma":0.0001959183,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002226328,"about_ca_topic_score_gemma":0.001968412,"domain_scores_codex":[0.9998389,0.00002355728,0.000004944227,0.00004606051,0.00005137088,0.00003515084],"domain_scores_gemma":[0.9998382,0.00006779619,0.00003440315,0.00001315203,0.00003275685,0.00001361079],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001193412,0.0000164243,0.0006346869,0.00005967309,0.000005002574,0.00004042592,0.00008027182,0.0004004278,0.9975292,0.0002234347,0.0000536925,0.0008373223],"study_design_scores_gemma":[0.000007218071,0.0001075727,0.00318098,0.000003750744,0.000003806715,0.00004956833,0.00003843488,0.002525155,0.9932771,0.00006349228,0.0007357308,0.000007129116],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9938287,0.0006094908,0.003210948,0.00006822652,0.00001006841,0.00001852891,0.0002164581,0.00004764118,0.001989872],"genre_scores_gemma":[0.9964712,0.0003487245,0.001937892,0.00002748296,0.000007292267,0.00002409547,0.00018656,0.00001430059,0.0009826767],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002278047,"threshold_uncertainty_score":0.007620871,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01325612461407985,"score_gpt":0.2792887154269562,"score_spread":0.2660325908128764,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}