{"id":"W7111508722","doi":"","title":"Non-Metal Catalyzed Heterodehydrocoupling of Phosphines and Hydrosilanes:Mechanistic Studies of B(C6F5)3-Mediated Formation of P-Si Bonds","year":2017,"lang":"en","type":"article","venue":"Explore Bristol Research","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"European Commission; Natural Sciences and Engineering Research Council of Canada; Government of Canada","keywords":"Hydrosilylation; Catalysis; Phosphine; Silane; Adduct; Silanes; Dissociation (chemistry); Lewis acids and bases","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006500558,0.0002142273,0.0006333843,0.0001299696,0.0002807292,0.00003646708,0.0005844829,0.0001750815,0.00008553245],"category_scores_gemma":[0.001552423,0.0002024364,0.00008326811,0.0001438916,0.0008707129,0.000285406,0.000503096,0.0003159531,0.000007484858],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007001714,"about_ca_system_score_gemma":0.00009473611,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002044011,"about_ca_topic_score_gemma":0.00004863687,"domain_scores_codex":[0.9978622,0.00001826861,0.0006618181,0.0003389122,0.0007560303,0.0003628234],"domain_scores_gemma":[0.997582,0.0002903653,0.0005370373,0.0008620359,0.0006051217,0.0001234675],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001433505,0.0001322927,0.004799629,0.002866457,0.00007579143,0.00001067676,0.002280502,0.000002888594,0.9890999,0.00001617297,0.0002401587,0.000332217],"study_design_scores_gemma":[0.0009819993,0.00007512994,0.0006822526,0.0004006666,0.00003148465,0.00001103075,0.002780395,0.001421308,0.9932352,0.0001794829,0.00003988594,0.0001611601],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978938,0.001228266,0.00001449671,0.0001012407,0.00004535911,0.0001389783,0.00009175656,0.00002235954,0.0004638096],"genre_scores_gemma":[0.9986737,0.0008804158,0.00007217093,0.000002926053,0.00006795707,0.00003034318,0.00007039795,0.00003663764,0.0001654763],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004135341,"threshold_uncertainty_score":0.8255118,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1032377268038873,"score_gpt":0.3738026487435221,"score_spread":0.2705649219396348,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}