{"id":"W7112737635","doi":"","title":"Tris-Silanide f-Block Complexes:Insights into Paramagnetic Influence on NMR Chemical Shifts","year":2024,"lang":"en","type":"article","venue":"Research Explorer (The University of Manchester)","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Natural Sciences and Engineering Research Council of Canada","funders":"","keywords":"Paramagnetism; Diamagnetism; Isostructural; NMR spectra database; Chemical shift; Carbon-13 NMR satellite; Spectral line; Nuclear magnetic resonance spectroscopy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006637195,0.0001783718,0.0001481032,0.00008954116,0.00009540436,0.0001381047,0.0002025154,0.0001808611,0.00105968],"category_scores_gemma":[0.0001269649,0.00007950779,0.00006525603,0.00007056756,0.0001262523,0.0001489413,0.0001221046,0.0002665432,0.0001800584],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002001558,"about_ca_system_score_gemma":0.00007114337,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003657528,"about_ca_topic_score_gemma":0.0006635715,"domain_scores_codex":[0.9999506,0.000006728383,0.000003537314,0.00001203265,0.00001613289,0.00001090152],"domain_scores_gemma":[0.9999446,0.00001367723,0.00001420338,0.000005434848,0.00001257118,0.000009621935],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006879999,0.000005610145,0.00007803744,0.00003455208,0.0000027008,0.00002090392,0.00002798889,0.00004725831,0.9986513,0.00004882984,0.00002941772,0.0009845309],"study_design_scores_gemma":[0.000007698873,0.0001497061,0.001632281,0.000002682706,0.000005308173,0.0001136523,0.00002780334,0.0004171232,0.9956971,0.00003208001,0.001910562,0.000003980881],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972542,0.0007846224,0.0007374298,0.00004001195,0.000005416603,0.000007658409,0.00007028344,0.00003398235,0.001066414],"genre_scores_gemma":[0.9971905,0.0004358463,0.001109033,0.00003115436,0.000004972632,0.000009784295,0.0001450057,0.00001903734,0.001054641],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00105968,"threshold_uncertainty_score":0.003544986,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04972759780888186,"score_gpt":0.3168108632446899,"score_spread":0.2670832654358081,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}