{"id":"W7114781038","doi":"10.1039/d5nj04250j","title":"Ammonia-free and one-pot synthesis of di-chloro silicon phthalocyanine and naphthalocyanine","year":2025,"lang":"en","type":"article","venue":"New Journal of Chemistry","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Phthalocyanine; Silicon; Copper phthalocyanine; Photodynamic therapy; Organic semiconductor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009784463,0.0002950882,0.0001918165,0.0001424113,0.0001184331,0.0001050043,0.0002952298,0.0002747083,0.001420136],"category_scores_gemma":[0.00009315935,0.0001325746,0.0001458886,0.0002301053,0.0001207314,0.0002660526,0.0002089602,0.0002819155,0.0004932501],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001762747,"about_ca_system_score_gemma":0.0002599417,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003224476,"about_ca_topic_score_gemma":0.0009128868,"domain_scores_codex":[0.9999223,0.000007820187,0.000005260932,0.00001489808,0.00002739272,0.00002231024],"domain_scores_gemma":[0.9999624,0.000005995432,0.000008751492,0.000006552595,0.000007378503,0.000008888264],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003625156,0.0000315635,0.000060162,0.0001549032,0.00000646692,0.0000961023,0.00002385484,0.0002780017,0.9920439,0.0005706297,0.0002166413,0.006481464],"study_design_scores_gemma":[0.00001468937,0.0001552075,0.0005719614,0.000003661197,0.000004842127,0.0001650193,0.000009931041,0.00112583,0.9928946,0.0001390848,0.004907217,0.000007949486],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9392339,0.003730172,0.03513577,0.0002992694,0.0001106813,0.000332257,0.00156185,0.0004988758,0.01909717],"genre_scores_gemma":[0.977926,0.001265019,0.01535109,0.00005205566,0.00001484764,0.0001393375,0.0005674281,0.00004445352,0.004639891],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001420136,"threshold_uncertainty_score":0.004750848,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009788244483147293,"score_gpt":0.233918257233123,"score_spread":0.2241300127499757,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}