{"id":"W7116086407","doi":"10.1021/photonsci.5c00030.s001","title":"Laboratory-BasedAmbient-Pressure X‑ray PhotoelectronSpectroscopy for Pressure up to 1 bar","year":2025,"lang":"","type":"article","venue":"Figshare","topic":"Electron and X-Ray Spectroscopy Techniques","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"X-ray photoelectron spectroscopy; Nozzle; Bar (unit); Supersonic speed; Ambient pressure; Characterization (materials science); Analytical Chemistry (journal); Spectroscopy; Supercritical fluid","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","scholarly_communication","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0005269733,0.00119822,0.00126354,0.0005710157,0.001000394,0.001070462,0.002385243,0.0008230586,0.2483735],"category_scores_gemma":[0.002293381,0.001287119,0.0004759208,0.00172389,0.00006713728,0.0006020373,0.0005691694,0.0008623317,0.0028612],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003533635,"about_ca_system_score_gemma":0.002251884,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000428749,"about_ca_topic_score_gemma":0.00006356126,"domain_scores_codex":[0.9926965,0.000338907,0.001076091,0.002338956,0.0008098087,0.002739745],"domain_scores_gemma":[0.9953089,0.0004139935,0.0004456607,0.001996754,0.001210515,0.0006242235],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004626152,0.0001427024,0.000009896928,0.001433961,0.0001368359,0.00000434453,0.0001748169,0.0000599085,0.4173763,0.001427702,0.5786974,0.00007359352],"study_design_scores_gemma":[0.0006352622,0.0008810727,0.00003821022,0.002258154,0.0002146397,8.736524e-7,0.00003067104,0.0004554573,0.5095109,0.0003094113,0.4850299,0.0006353834],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"dataset","genre_gemma":"empirical","genre_scores_codex":[0.001850142,0.02092348,0.002431578,0.003788172,0.002382517,0.01122855,0.9498667,0.002069474,0.005459383],"genre_scores_gemma":[0.7395753,0.0003199621,0.01889884,0.02364469,0.002813458,0.03019775,0.08398553,0.0009229516,0.0996415],"genre_candidate":"dataset","genre_consensus":null,"teacher_disagreement_score":0.8658811,"threshold_uncertainty_score":0.9999665,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01495384218473777,"score_gpt":0.3076516118825843,"score_spread":0.2926977696978466,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}