{"id":"W7116790158","doi":"10.1021/acs.chemrev.5c00531","title":"Paramagnetic Transition Metal Hydride Complexes","year":2025,"lang":"en","type":"article","venue":"Chemical Reviews","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Paramagnetism; Hydride; Diamagnetism; Stoichiometry; Hyperfine structure; Octahedron; Antiferromagnetism; Transition metal; Magnetic moment","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001544164,0.0001978167,0.0005681618,0.0000402475,0.0000522892,0.00003295737,0.0002943532,0.00007952299,0.02461371],"category_scores_gemma":[0.0001961209,0.0001652172,0.0003936979,0.000276845,0.0000889697,0.00004742344,0.00005557663,0.0001477759,0.0002536543],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004710912,"about_ca_system_score_gemma":0.00001814714,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000009996746,"about_ca_topic_score_gemma":0.000002009457,"domain_scores_codex":[0.9988093,0.00002083194,0.0004840254,0.0003371382,0.0001284529,0.0002202208],"domain_scores_gemma":[0.9992248,0.0001070088,0.00007737464,0.0004875633,0.00002173899,0.00008149747],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00000560641,0.00007419992,0.000006827825,0.0003170046,0.00003973951,0.000001098685,0.00002446509,2.234338e-7,0.8372083,0.0005743519,0.001125577,0.1606227],"study_design_scores_gemma":[0.0001324831,0.000002097132,0.00001426703,0.000123125,0.0001964227,0.000002567142,0.0000137303,0.00006957634,0.4010485,0.0007311018,0.5975277,0.0001384309],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6616828,0.07556733,0.001252591,0.001840148,0.00009933718,0.0003088811,0.00003857314,0.000234387,0.258976],"genre_scores_gemma":[0.9839169,0.003877572,0.001000799,0.0007991475,0.0001730207,0.0001592851,0.0001962166,0.0000283374,0.00984875],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5964021,"threshold_uncertainty_score":0.9762779,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0204798276882514,"score_gpt":0.26462315888076,"score_spread":0.2441433311925086,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}