{"id":"W7117301849","doi":"10.1021/acsestengg.5c00919","title":"Selective and Solvent-Free Extraction of Medium-Chain Carboxylic Acids with Poly(dimethylsiloxane) Membranes","year":2025,"lang":"en","type":"article","venue":"ACS ES&T Engineering","topic":"Extraction and Separation Processes","field":"Engineering","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Ontario Water Consortium","keywords":"Membrane; Polydimethylsiloxane; Selectivity; Extraction (chemistry); Acetic acid; Carboxylic acid; Membrane technology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002848887,0.00051893,0.0002225373,0.0002197727,0.0002265471,0.0002534208,0.0002551433,0.000317004,0.0003815591],"category_scores_gemma":[0.000228907,0.0001759963,0.0004026122,0.0001962446,0.0001938661,0.000430119,0.0002234568,0.0003275762,0.0002681431],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003943962,"about_ca_system_score_gemma":0.0003019163,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008662459,"about_ca_topic_score_gemma":0.001466387,"domain_scores_codex":[0.9998073,0.00001818885,0.0000169785,0.00004145103,0.0000699407,0.00004618062],"domain_scores_gemma":[0.9998704,0.0000450743,0.00003933971,0.000008962843,0.00002524064,0.00001087734],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001199198,0.000005462262,0.0000518034,0.00003099736,0.000002151799,0.00002029457,0.000005728732,0.0001270003,0.9992866,0.00003101543,0.000006518851,0.0004203445],"study_design_scores_gemma":[0.000001586803,0.00003160375,0.0002598951,0.000001310234,0.000002338591,0.00001270703,0.000005391029,0.0006732161,0.9987795,0.000007331289,0.0002231254,0.000002082498],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.981808,0.001069956,0.01523508,0.00005847053,0.00002049355,0.00006858746,0.0004147536,0.0000874905,0.001237167],"genre_scores_gemma":[0.9755147,0.001615864,0.02121289,0.00003050923,0.00001021881,0.00006786537,0.0003141351,0.00001782552,0.001216],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008662459,"threshold_uncertainty_score":0.0028615,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005026626914472911,"score_gpt":0.2192539159801363,"score_spread":0.2142272890656634,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}