{"id":"W7132215143","doi":"","title":"Asymmetric synthesis of polyhydroxylated zinolizidines from C-glycosides by One-pot double conjugate addition.","year":2007,"lang":"en","type":"article","venue":"NPARC","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Enantioselective synthesis; Conjugate; Sequence (biology); Yield (engineering); Ideal (ethics)","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001439135,0.0005960006,0.0003404194,0.0002863434,0.000229085,0.0003154682,0.0005194504,0.0003023654,0.00270357],"category_scores_gemma":[0.0001272798,0.0002400766,0.0002364208,0.0003212114,0.0001948943,0.0005336361,0.00049304,0.0007821852,0.001259965],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003813337,"about_ca_system_score_gemma":0.0004449853,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004843693,"about_ca_topic_score_gemma":0.001285451,"domain_scores_codex":[0.999899,0.000009640454,0.00000973661,0.00002226115,0.000019569,0.00003972205],"domain_scores_gemma":[0.9999523,0.000004830279,0.00001495251,0.000006084513,0.00000713066,0.00001469647],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003220725,0.0001838009,0.0001841736,0.0004797594,0.00004570308,0.0005652715,0.0001589924,0.0009887506,0.9506357,0.006000891,0.001253344,0.03918153],"study_design_scores_gemma":[0.0000787172,0.0003866302,0.000404495,0.00001192118,0.00002398954,0.0002620855,0.00001891266,0.0007543224,0.9863929,0.0003378621,0.01130892,0.00001918744],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8093836,0.008192007,0.1280683,0.0006541071,0.0009110733,0.0009838996,0.001990587,0.000823083,0.04899334],"genre_scores_gemma":[0.9571,0.004446602,0.02328539,0.0001319714,0.00004558903,0.0001950317,0.0005956164,0.00007079213,0.01412896],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00270357,"threshold_uncertainty_score":0.009044349,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01503214875809136,"score_gpt":0.2239619329639027,"score_spread":0.2089297842058113,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}