{"id":"W7132977947","doi":"","title":"Organoboron Catalysis as a Strategy for the Regioselective Functionalization of Ambident Nitrogen Heterocycles","year":2023,"lang":"","type":"dissertation","venue":"TSpace","topic":"Inorganic and Organometallic Chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"University of Toronto","keywords":"Regioselectivity; Allylic rearrangement; Heteroatom; Catalysis; Ring (chemistry); Nitrogen","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001335849,0.0004094857,0.0001280747,0.0002223093,0.0001327531,0.0002430692,0.0002265581,0.0001549856,0.001221287],"category_scores_gemma":[0.00005235108,0.0001124825,0.0001437671,0.000140259,0.0001935102,0.0002412059,0.0003091463,0.0004194049,0.0004433784],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002788489,"about_ca_system_score_gemma":0.0002588624,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004717973,"about_ca_topic_score_gemma":0.001213379,"domain_scores_codex":[0.9999084,0.00001398685,0.000004744865,0.00002149574,0.00002834197,0.00002290135],"domain_scores_gemma":[0.9999872,0.00000215623,0.000003829458,0.000001572887,0.000002024892,0.000003215394],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003080408,0.00005111133,0.00006126718,0.0001779531,0.000007234956,0.0001166022,0.00004687382,0.000446321,0.9810565,0.003109636,0.0002141739,0.01468152],"study_design_scores_gemma":[0.000009405025,0.0001857827,0.0002876043,0.0000187888,0.000008979886,0.0002240809,0.00002149781,0.0007304343,0.9795834,0.0003508205,0.01857173,0.000007306585],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8292765,0.02437209,0.06236861,0.0004030693,0.0001666319,0.0002011176,0.0002408845,0.0002775516,0.08269343],"genre_scores_gemma":[0.9525831,0.01452447,0.01486228,0.0001047986,0.00003447757,0.0000705558,0.0002210386,0.00004984135,0.01754935],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001221287,"threshold_uncertainty_score":0.00408566,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0258599619536499,"score_gpt":0.3218519637003937,"score_spread":0.2959920017467437,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}