{"id":"W7133080222","doi":"","title":"Total synthesis of Callystatin A and C-9-epi-Callystatin A","year":2002,"lang":"","type":"dissertation","venue":"TSpace","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"University of Toronto","keywords":"Total synthesis; Wittig reaction; Lactone; Fragment (logic); Peptide fragment","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.0008607159,0.001339621,0.002181078,0.000173373,0.0001982041,0.0001102026,0.0006505253,0.001547707,0.02440873],"category_scores_gemma":[0.007279761,0.001542663,0.0004887703,0.0005029746,0.0004494291,0.00008374291,0.000205731,0.001150132,0.00007783985],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002546248,"about_ca_system_score_gemma":0.0004236866,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006821492,"about_ca_topic_score_gemma":0.00003665082,"domain_scores_codex":[0.9940676,0.0003542911,0.001832357,0.001638627,0.00114415,0.0009629724],"domain_scores_gemma":[0.9918,0.003820682,0.001908557,0.001492884,0.0004322124,0.0005456765],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003550659,0.0004971442,0.000139493,0.00785592,0.000656693,0.00007879006,0.02487477,0.000005300907,0.9127067,0.000037837,0.0004635885,0.05232874],"study_design_scores_gemma":[0.0009850364,0.00007080836,0.0002492733,0.0024942,0.001289812,0.0002234857,0.03793215,0.001313007,0.9535691,0.00007046279,0.0004988752,0.00130375],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9191497,0.002577084,0.0003554989,0.0003369672,0.0003223434,0.0004204424,0.0002535974,0.0001202656,0.07646409],"genre_scores_gemma":[0.8698509,0.0009864786,0.02780282,0.00001779433,0.0002928659,0.0001654897,0.0001575497,0.0003705882,0.1003555],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05102498,"threshold_uncertainty_score":0.9999355,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01879739130427044,"score_gpt":0.3251024835016302,"score_spread":0.3063050921973597,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}