{"id":"W7140685096","doi":"10.1333/s00897072011a","title":"A Microscale Heck Reaction In Water","year":2007,"lang":"en","type":"article","venue":"The Chemical Educator","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Heck reaction; Microscale chemistry; Sodium carbonate; Catalysis; Acrylic acid; Green chemistry; Sodium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001686828,0.0005086382,0.0003303231,0.0002492729,0.0003471616,0.0005483734,0.0004765331,0.0004954634,0.009014041],"category_scores_gemma":[0.0001827367,0.0003195175,0.0002874569,0.0002653909,0.000245006,0.001046911,0.0006902569,0.001048081,0.006427116],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003792607,"about_ca_system_score_gemma":0.0003680322,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004283544,"about_ca_topic_score_gemma":0.001133734,"domain_scores_codex":[0.9996649,0.00001915273,0.00001604853,0.000138813,0.0001136085,0.00004744172],"domain_scores_gemma":[0.9999468,0.00001070445,0.00001088807,0.00001444976,0.000006527732,0.00001057294],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006642617,0.000116382,0.0001699577,0.0002849249,0.00001943472,0.0002490602,0.0001040197,0.0004659663,0.9341025,0.004196858,0.003393456,0.05683082],"study_design_scores_gemma":[0.00002331644,0.0004259332,0.0004215612,0.00001422777,0.00001623713,0.0003646603,0.00004293953,0.000873306,0.8918712,0.0006779942,0.1052384,0.00003024488],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4283522,0.01090087,0.3809645,0.002036092,0.00231333,0.002483981,0.00327563,0.01186594,0.1578074],"genre_scores_gemma":[0.6699223,0.007107053,0.2164512,0.0006723444,0.0004727341,0.001038842,0.002052206,0.0004712792,0.1018121],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009014041,"threshold_uncertainty_score":0.03015494,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009311053087362076,"score_gpt":0.2789530929776653,"score_spread":0.2696420398903032,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}