{"id":"W771401668","doi":"10.71781/11509","title":"Préparation de carbénoïdes gem-dizinciques : étude de réactivité et application à la synthèse stéréosélective de dérivés cyclopropanes 1,2,3-substitués via cyclopropylzinciques","year":2004,"lang":"fr","type":"dissertation","venue":"Open MIND","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Carbenoid; Chemistry; Allylic rearrangement; Electrophile; Cyclopropane; Medicinal chemistry; Substituent; Halogen; Reagent; Cyclobutane; Cyclopropanation; Stereochemistry; Organic chemistry; Ring (chemistry); Alkyl; Rhodium; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002308628,0.0003369567,0.0002671574,0.0003012372,0.0002231005,0.0002331659,0.0002800686,0.0002638542,0.002606748],"category_scores_gemma":[0.0003451176,0.0001666243,0.0001549745,0.0002835531,0.0002038963,0.0002959836,0.0001793454,0.0006387935,0.0005179429],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003601888,"about_ca_system_score_gemma":0.0003673177,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001907997,"about_ca_topic_score_gemma":0.004239896,"domain_scores_codex":[0.9998548,0.00001648893,0.000007283582,0.00003900981,0.00003799318,0.00004444116],"domain_scores_gemma":[0.9998946,0.0000244648,0.00002202114,0.0000201447,0.00002285613,0.00001580118],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002446428,0.00004348241,0.0003118133,0.0001625207,0.00001516349,0.00008569363,0.0001027138,0.0002498558,0.9904035,0.0004818242,0.0001408758,0.00775799],"study_design_scores_gemma":[0.00002251131,0.000170565,0.0008750756,0.000005341552,0.00001167991,0.0000624522,0.00001249192,0.0001771705,0.9954532,0.00002099285,0.003183295,0.000005205068],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9780989,0.004172332,0.007612238,0.0001082204,0.00005578846,0.0002381968,0.0005527191,0.0001151607,0.009046573],"genre_scores_gemma":[0.9859925,0.002622277,0.004250575,0.0000512208,0.00001063323,0.00006741476,0.000565897,0.00004982063,0.006389758],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002606748,"threshold_uncertainty_score":0.008720458,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01794137921672709,"score_gpt":0.3321237420082099,"score_spread":0.3141823627914828,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}