{"id":"W777953804","doi":"10.1021/jp035905o","title":"Measurements of the Rate Constant of HO<sub>2</sub> + NO<sub>2</sub> + N<sub>2</sub> → HO<sub>2</sub>NO<sub>2</sub> + N<sub>2</sub> Using Near-Infrared Wavelength-Modulation Spectroscopy and UV−Visible Absorption Spectroscopy","year":2003,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Chemistry; Spectroscopy; Infrared spectroscopy; Absorption spectroscopy; Infrared; Torr; Ultraviolet visible spectroscopy; Wavelength; Reaction rate constant; Absorption (acoustics); Analytical Chemistry (journal); Optics; Kinetics; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007834235,0.0004820895,0.0003256782,0.0001909238,0.0002480058,0.0002527182,0.0006204604,0.0003929214,0.001015196],"category_scores_gemma":[0.001430587,0.0002504502,0.0002545403,0.0001826125,0.0003472096,0.0005500381,0.0002455899,0.0007920431,0.0003540154],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004823398,"about_ca_system_score_gemma":0.0002562435,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00167907,"about_ca_topic_score_gemma":0.001665291,"domain_scores_codex":[0.9997347,0.0000330582,0.00001132892,0.00007223997,0.00009361466,0.00005499597],"domain_scores_gemma":[0.9992894,0.0003227093,0.0001269896,0.00007103518,0.0001484892,0.00004126997],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002278027,0.00004398508,0.002127456,0.00009935511,0.00001519356,0.00003944147,0.0001137311,0.0004405009,0.993288,0.0002228776,0.00009874584,0.003283059],"study_design_scores_gemma":[0.000007579635,0.0001534245,0.005698248,0.000004208295,0.00001201916,0.00005331325,0.00003977562,0.00386796,0.9893147,0.00006130456,0.000775153,0.00001234332],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9804807,0.0007744912,0.01589004,0.0001101179,0.00004449516,0.0001196186,0.0004977862,0.0001996971,0.001883033],"genre_scores_gemma":[0.9895098,0.0009908322,0.00716135,0.00001988645,0.00001379845,0.0001188227,0.0003360251,0.00003910458,0.001810445],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00167907,"threshold_uncertainty_score":0.004143238,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01468155075884048,"score_gpt":0.2199294214025412,"score_spread":0.2052478706437008,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}