{"id":"W96365122","doi":"10.1021/ic000598b","title":"Selenium Imides:  <sup>77</sup>Se NMR Investigations of the SeCl<sub>2</sub>−<sup>t</sup>BuNH<sub>2</sub> Reaction and X-ray Structures of Se<sub>3</sub>(N<sup>t</sup>Bu)<sub>3</sub>, <sup>t</sup>BuNSe(<i>μ</i>-N<sup>t</sup>Bu)<sub>2</sub>SO<sub>2</sub>, and <sup>t</sup>BuNSe(<i>μ</i><i>-</i>N<sup>t</sup>Bu)<sub>2</sub>SeO","year":2000,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Cycloaddition; Toluene; Nuclear magnetic resonance spectroscopy; Chalcogen; Crystallography; Selenium; NMR spectra database; Crystal structure; Stereochemistry; Spectral line; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity","insufficient_payload"],"category_scores_codex":[0.005851773,0.01466486,0.0135788,0.003788518,0.007319096,0.004512036,0.01150485,0.01103314,0.00236241],"category_scores_gemma":[0.005496238,0.0157873,0.006428427,0.01246164,0.009634417,0.007584096,0.005999485,0.01364226,0.001531721],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.005472216,"about_ca_system_score_gemma":0.007187074,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005827553,"about_ca_topic_score_gemma":0.0002553155,"domain_scores_codex":[0.9406549,0.00353595,0.0170128,0.01527811,0.01121158,0.01230665],"domain_scores_gemma":[0.9557492,0.005986535,0.009775981,0.01509561,0.005557911,0.007834754],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002668629,0.004891696,0.003696242,0.006609663,0.005852518,0.0005860656,0.01621721,0.03467055,0.8973379,0.0002270491,0.01122145,0.01602102],"study_design_scores_gemma":[0.01506777,0.001030797,0.001816318,0.004371445,0.006115816,0.004470948,0.0123015,0.03688758,0.8947015,0.001928877,0.008001274,0.01330621],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9671841,0.005915681,0.0003584044,0.002833122,0.0009462588,0.006991107,0.009743334,0.004253338,0.001774689],"genre_scores_gemma":[0.9572762,0.01603333,0.0006576219,0.003264639,0.007049928,0.001945035,0.00859003,0.004619271,0.000563891],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0150943,"threshold_uncertainty_score":0.9992457,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.010541351285872,"score_gpt":0.2050443770027049,"score_spread":0.1945030257168329,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}