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Record W1577297561 · doi:10.5772/58929

Corrosion and Surface Treatment of Magnesium Alloys

2014· book-chapter· en· W1577297561 on OpenAlexaff
Henry Hu, Xueyuan Nie, Yueyu Ma

Bibliographic record

VenueInTech eBooks · 2014
Typebook-chapter
Languageen
FieldMaterials Science
TopicMagnesium Alloys: Properties and Applications
Canadian institutionsUniversity of Windsor
Fundersnot available
KeywordsMagnesiumMaterials scienceMetallurgyCorrosion

Abstract

fetched live from OpenAlex

fuel supplies and arising environmental problems associated with fuel emission products.Magnesium alloys are a promising alternative to the aluminium alloys currently dominating the transportation industry.However, the limited use of magnesium in engineering applications results mainly from the shortcomings including high reactivity in the molten state, inferior fatigue and creep properties compared to aluminium, poor corrosion and wear resistance [22].One of the main challenges in the use of magnesium, particularly for outdoor application, is to overcome its poor corrosion resistance.Magnesium and its alloys are extremely susceptible to galvanic corrosion, which can cause severe attack in the metal resulting in decreased mechanical stability and an unattractive appearance.Corrosion can be minimized by the use of high purity alloys in which the heavy metal impurities such as iron, nickel and copper are kept below a threshold value.The elimination of bad design, surface contamination, galvanic couples and inadequate or incorrectly applied surface protection schemes can also significantly decrease the corrosion rate of magnesium alloys in service [3].In this chapter, the corrosion characteristic of Mg and Mg alloys are described.Fundamental aspects of magnesium corrosion such as general corrosion, galvanic corrosion, pitting, stress corrosion and corrosion fatigue are reviewed.The factors that control the corrosion behaviour of Mg and Mg alloys are discussed in some detail.Finally, the more recently developed corrosion science and engineering underpinning various surface treatment methods such as electrochemical plating, conversion coating, anodizing, gas-phase coating, organic coating, electrolytic plasma oxidation for magnesium alloys are described. Corrosion characteristics of pure magnesiumMagnesium, like most metals and alloys, relies on a natural surface film to control its corrosion.However, the nature of this film is not thoroughly understood.Good passive films are those that restrict the outward flow of cations, resist the inward flow of damaging anions or oxidants, and rapidly repair themselves in the event of localized breakdown.The structure and composition of the surface films, which depends strongly on environmental and metallurgical factors, such as electrolyte species and impurities in the metal, determine the protective ability of a passive film. Environmental effectsNo material shows high corrosion resistance in all kinds of environments.The high corrosion resistance of materials always refers to some specific environments.Magnesium has its own preferred service environments.However, there are fewer media that are suitable for the magnesium and magnesium alloys compared with other materials, such as steels and aluminum alloys.For example, magnesium and magnesium alloys are usually stable in basic solutions, but in neutral and acidic media they dissolve at high rates [3].This is quite different from aluminum alloys that are normally stable in neutral media but are unstable in both basic and acidic solutions.Magnesium Alloys -Properties in Solid and Liquid States Pb -Pb +2 -0.126 Sn -Sn +2 -0.136 Ni -Ni +2 -0.250 Co -Co +2 -0.277 Cd -Cd +2 -0.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.003
Threshold uncertainty score0.009

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0000.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0030.003

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.023
GPT teacher head0.232
Teacher spread0.208 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreReview

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations75
Published2014
Admission routes1
Has abstractyes

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