The Role of Copper on the Crevice Corrosion Behavior of Nickel-Chromium-Molybdenum Alloys in Aggressive Solutions
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Bibliographic record
Abstract
The effect of Cu on the localized corrosion of Ni-Cr-Mo alloys has been investigated in hot saline solutions by comparing the behavior of N06059 and N06200 alloys, using electrochemical and surface analytical techniques. No measurable effect of copper on anodic film growth kinetics and passive film properties was detected and the breakdown and repassivation potentials of the alloys were very similar. Angle-resolved x-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectroscopy demonstrated that the copper segregated to the oxide/solution interface during anodic film growth and that this process was enhanced as the pH decreased, as would occur in a crevice prior to initiation. Galvanostatically controlled crevice corrosion experiments demonstrated that this surface accumulation suppressed the metastable breakdown events that preceded initiation on the Cu-free alloy. Dynamic secondary ion mass spectrometry showed that copper accumulated with molybdates in crevice corroded locations but could not confirm any influence of copper on crevice propagation.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it