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Record W1973894806 · doi:10.1021/es902237f

Quantification of Analytical Recovery in Particle and Microorganism Enumeration Methods

2010· article· en· W1973894806 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueEnvironmental Science & Technology · 2010
Typearticle
Languageen
FieldEnvironmental Science
TopicWater Quality and Resources Studies
Canadian institutionsUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of CanadaUniversity of WaterlooCanadian Water Network
KeywordsEnumerationSeedingMonte Carlo methodStatisticsSampling (signal processing)Probabilistic logicSample (material)Particle numberSample size determinationBiological systemStatistical modelMathematicsComputer scienceChemistryChromatographyVolume (thermodynamics)Physics

Abstract

fetched live from OpenAlex

Enumeration-based methods that are often used to quantify microorganisms and microscopic discrete particles in aqueous systems may include losses during sample processing or errors in counting. Analytical recovery (the capacity of the analyst to successfully count each microorganism or particle of interest in a sample using a specific enumeration method) is frequently assessed by enumerating samples that are seeded with known quantities of the microorganisms or particles. Probabilistic models were developed to account for the impacts of seeding and analytical error on recovery data, and probability intervals, obtained by Monte Carlo simulation, were used to evaluate recovery experiment design (i.e., seeding method, number of seeded particles, and number of samples). The method of moments, maximum likelihood estimation, and credible intervals were used to statistically analyze recovery experiment results. Low or uncertain numbers of seeded particles were found to result in variability in recovery data that was not due to analytical recovery, and should be avoided if possible. This additional variability was found to reduce the reproducibility of experimental results and necessitated the use of statistical analysis techniques, such as maximum likelihood estimation using probabilistic models that account for the impacts of sampling and analytical error in recovery data.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesScience and technology studies
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.160
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.003
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.023
GPT teacher head0.281
Teacher spread0.257 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it