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Colloidal PbS Nanocrystals with Size‐Tunable Near‐Infrared Emission: Observation of Post‐Synthesis Self‐Narrowing of the Particle Size Distribution

2003· article· en· 1,808 citations· W2011257287 on OpenAlex· 10.1002/adma.200305395

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A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

Canadian affiliationAn author listed a Canadian institution. This is the only route the usual frame has.

Machine scores (provisional)

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

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Opus teacher head0.011
GPT teacher head0.211
Teacher spread
0.200 · how far apart the two teachers sit on this one work
Validation status
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Abstract

The synthesis of nanocrystalline PbS quantum dots using organometallic precursors is reported. The samples exhibit tunable, strong near‐infrared photoluminescence. A remarkable spontaneous self‐directed narrowing of the particle size distribution is shown to occur after the particles are synthesized and dispersed in organic solvent. The Figure shows the tuning of band‐edge exciton absorption features through the near‐infrared spectral region according to particle size.

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The record

Venue
Advanced Materials
Topic
Quantum Dots Synthesis And Properties
Field
Materials Science
Canadian institutions
University of Toronto
Funders
Keywords
Materials sciencePhotoluminescenceNanocrystalline materialNanocrystalQuantum dotParticle sizeInfraredParticle-size distributionColloidAbsorption edgeAbsorption (acoustics)NanoparticleParticle (ecology)ExcitonNanotechnologySolventBand gapOptoelectronicsChemical engineeringOpticsCondensed matter physicsOrganic chemistryComposite material
Has abstract in OpenAlex
yes