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Thin-Film Composite Polyamide Membranes Functionalized with Biocidal Graphene Oxide Nanosheets

2013· article· en· 530 citations· W2029551729 on OpenAlex· 10.1021/ez4001356

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A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

Canadian funderA Canadian agency funded it. The work may carry no Canadian affiliation at all.

No Canadian affiliation. An affiliation-only frame — the usual design — would never have seen this work. It is one of the works that make the case for inverting the frame.

Machine scores (provisional)

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Opus teacher head0.003
GPT teacher head0.158
Teacher spread
0.155 · how far apart the two teachers sit on this one work
Validation status
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Abstract

Fouling of membranes by microorganisms is a major limiting factor in membrane separation processes. Novel strategies are therefore required to decrease the extent of bacterial growth on membranes. In this study, we confer strong antimicrobial properties to thin-film composite polyamide membranes by a simple graphene oxide surface functionalization. Using amide coupling between carboxyl groups of graphene oxide and carboxyl groups of the polyamide active layer, graphene oxide is irreversibly bound to the membrane. Surface binding of graphene oxide is demonstrated by scanning electron microscopy and Raman spectroscopy. Direct contact of bacteria with functionalized graphene oxide on the membrane surface results in 65% bacterial inactivation after 1 h of contact time. This bactericidal effect is imparted to the membrane without any detrimental effect to the intrinsic membrane transport properties. Our results suggest that functionalization of thin-film composite membranes with graphene oxide nanosheets is a promising approach for the development of novel antimicrobial membranes.

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The record

Venue
Environmental Science & Technology Letters
Topic
Graphene and Nanomaterials Applications
Field
Engineering
Canadian institutions
Funders
Division of Chemical, Bioengineering, Environmental, and Transport SystemsNatural Sciences and Engineering Research Council of CanadaDivision of Materials ResearchMaterials Research Science and Engineering Center, Harvard UniversityNational Science Foundation
Keywords
GrapheneMembranePolyamideOxideMaterials scienceSurface modificationThin-film composite membraneChemical engineeringNanotechnologyPolymer chemistryChemistryReverse osmosis
Has abstract in OpenAlex
yes