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Record W2032608903 · doi:10.2118/140860-ms

Selection of the Right Demulsifier for Chemical Enhanced Oil Recovery

2011· article· en· W2032608903 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueSPE International Symposium on Oilfield Chemistry · 2011
Typearticle
Languageen
FieldEngineering
TopicEnhanced Oil Recovery Techniques
Canadian institutionsNalco (Canada)
FundersRice University
KeywordsDemulsifierEmulsionPulmonary surfactantCationic polymerizationPolymerAmmoniumChemical engineeringProduced waterChemistryAlkylAmmonium bromideChromatographyOrganic chemistryEnvironmental engineering

Abstract

fetched live from OpenAlex

Abstract In this paper, the importance of five process variables (alkaline, surfactant, polymer, shear rate and oil cut) and their interactions that govern emulsion stability in chemical enhanced oil recovery (CEOR) was investigated. The surfactant, alkaline, and polymer decreased the size of oil droplets, increased the surface charge of oil droplets, and increased the film elasticity, making oil-water separation difficult. Selected cationic demulsifiers (patents pending) when added to a produced emulsion at ambient temperature for alkaline, surfactant, polymer (ASP) and surfactant, polymer (SP) processes yielded oil and water phases with greatly improved quality compared to emulsions treated with conventional nonionic demulsifier resins and polymeric cationic flocculants. Structure and performance relationships of alkyltrimethylammonium bromides and alkyldimethylbenzylammonium bromides (n=C8 to C18) were also studied. Octyltrimethylammonium bromide was the best demulsifier for SP flood and dodecyldimethylbenzylammonium bromide was the most effective for ASP flood. Di-alkyl quaternary ammonium bromides were more effective than mono-alkyl quaternary ammonium bromides of similar molecular weights. The zeta potential became less negative and the size of oil droplets remarkably increased when a cationic demulsifier was added to the emulsion. Application of this novel demulsifier resulted in the production of dry oil and clean water for a pilot field experiencing chemical breakthrough from an ASP flood

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.606
Threshold uncertainty score0.701

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.211
Teacher spread0.204 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it