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Record W2039507143 · doi:10.1021/ef060463b

Reversible Aging in Asphalt Binders

2007· article· en· W2039507143 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueEnergy & Fuels · 2007
Typearticle
Languageen
FieldChemistry
TopicPetroleum Processing and Analysis
Canadian institutionsQueen's University
FundersMinistère des TransportsNatural Sciences and Engineering Research Council of CanadaQueen's University
KeywordsAsphalteneAsphaltRheologyMaterials scienceWaxCrystallizationColloidComposite materialChemical engineering

Abstract

fetched live from OpenAlex

X-ray diffraction, optical microscopy, and mass spectrometry techniques were used in an attempt to clarify the morphological and chemical features that are responsible for reversible aging processes that occur in asphalt binders during conditioning at low temperatures. The reversible aging term is used in this paper to capture all reversible processes (i.e., wax crystallization, free volume collapse, asphaltene aggregation, etc.) that lead to a reduction in low-temperature rheological and fracture performance. Crystalline content and asphaltene aggregate size at ambient temperatures, as measured by X-ray diffraction on thin asphalt films, are identified as two factors that correlate reasonably well with the reversible aging tendency at low temperatures. A coarse and unstable colloidal state for the asphaltene fraction is also identified as an important contributor to reversible aging. It was found that the saturates fraction has a particularly significant role in the aging process, with those asphalts containing higher amounts of linear paraffin losing more in terms of rheological performance. This important phenomenon is responsible for significant fracture distress in asphalt pavements in northern climates and therefore deserves further investigation. Some of the air-blown asphalts investigated in this study were found to show a high crystalline content and a coarse phase morphology and concurrent tendency for reversible aging during cold conditioning. This may be due to the crude source(s) employed, the chemistry of the air-blowing process, or resulting phase changes. Other air-blown binders did not show these features while they were still susceptible to reversible aging. Hence, the reason for this behavior appears to be due to multiple processes which are at present only poorly understood.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.206
Threshold uncertainty score0.515

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.241
Teacher spread0.230 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it