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Record W2045928627 · doi:10.1021/cm047709f

Highly Efficient Electrophosphorescent Devices with Saturated Red Emission from a Neutral Osmium Complex

2005· article· en· W2045928627 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueChemistry of Materials · 2005
Typearticle
Languageen
FieldEngineering
TopicOrganic Light-Emitting Diodes Research
Canadian institutionsNational Research Council CanadaSteacie Institute for Molecular Sciences
Fundersnot available
KeywordsChromaticityIridiumOLEDPhosphorescenceMaterials scienceLuminous efficacyOsmiumQuantum efficiencyExcitonPolymerOptoelectronicsLayer (electronics)Light-emitting diodeDiodeElectronElectroluminescenceChemistryNanotechnologyOpticsRutheniumPhysicsOrganic chemistryFluorescenceCondensed matter physicsCatalysis

Abstract

fetched live from OpenAlex

Highly efficient electrophosphorescent polymer light-emitting diodes (LEDs) with saturated red emission (Commission Internationale de L'Eclairage chromaticity coordinates exactly at x = 0.67, y = 0.33) are achieved by blending a novel neutral Osmium complex into a single-component bipolar polymer host that possesses balanced hole- and electron-transporting ability. By using a tetraphenylenebiphenyldiamine (TPD)-based cross-linkable hole-transport layer as well as a layer of 1,3,5-tris( N -phenylbenzimidazol-2-yl)benzene (TPBI) as an electron-transport layer, a device structure with both effective hole/electron injection and efficient carriers/excitons blocking or confinement at both electrode sides is constituted. In this way, external quantum efficiency 12.8% is reached the first time with an organometallic complex with heavy metal core other than iridium.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.965

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.216
Teacher spread0.207 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it