MétaCan
Menu
Back to cohort
Record W2049154504 · doi:10.1002/cem.700

An investigation of orthogonal signal correction algorithms and their characteristics

2002· article· en· W2049154504 on OpenAlexaff
Olof Svensson, Theodora Kourti, John F. MacGregor

Bibliographic record

VenueJournal of Chemometrics · 2002
Typearticle
Languageen
FieldChemistry
TopicSpectroscopy and Chemometric Analyses
Canadian institutionsMcMaster University
Fundersnot available
KeywordsOrthogonalizationAlgorithmCalibrationComputer scienceComponent (thermodynamics)Point (geometry)Orthographic projectionGroup (periodic table)SIGNAL (programming language)Interpretation (philosophy)Orthogonal transformationComponent analysisPrincipal component analysisOrthogonal matrixProjection (relational algebra)Orthogonal arrayMathematicsArtificial intelligenceOrthogonal basisStatisticsMachine learningTaguchi methods

Abstract

fetched live from OpenAlex

Abstract Six different algorithms for orthogonal signal correction (OSC) are studied and compared both from an algorithmic point of view and from a prediction and analysis point of view. The algorithms have appeared under the names OSC (three alternative algorithms), direct orthogonalization (DO) and orthogonal projection to latent structures (OPLS). These algorithms can be divided into two groups. The first group has the ability to reduce the number of PLS components in the calibration models significantly by removing only one orthogonal component. The second group reduces the complexity of the calibration model by one PLS component for each orthogonal component removed. The methods are evaluated and compared using both simulated and real calibration data sets. In some cases the OSC algorithms can have quite different behaviors, such as when non‐linearities are present. However, in all cases we have studied, none of the OSC algorithms provided a significant improvement in the calibration models over using PLS on the raw data. The main advantage with OSC may lie in the possibly easier interpretation and understanding from the analysis of corrected data. Analysis of the orthogonal information removed with OSC might also be beneficial. Copyright © 2002 John Wiley & Sons, Ltd.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.009
metaresearch head score (Gemma)0.032
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: none
GenreCandidate signal: Methods · Consensus signal: Methods
Teacher disagreement score0.009
Threshold uncertainty score0.049

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0090.032
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0020.003
Science and technology studies0.0010.001
Scholarly communication0.0020.003
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.024
GPT teacher head0.251
Teacher spread0.227 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations165
Published2002
Admission routes1
Has abstractyes

Explore more

Same venueJournal of ChemometricsSame topicSpectroscopy and Chemometric AnalysesFrench-language works237,207