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Record W2065089439 · doi:10.1016/j.proeng.2014.09.003

There and Back Again 2.5Again Who did What in Solvent Extraction? A Demonstrated & Proven Technology for Uranium Recovery from Phosphoric Acid

2014· article· en· W2065089439 on OpenAlexaboutno aff
Vaughn Astley, Regis Stana

Bibliographic record

VenueProcedia Engineering · 2014
Typearticle
Languageen
FieldChemistry
TopicRadioactive element chemistry and processing
Canadian institutionsnot available
Fundersnot available
KeywordsUraniumPhosphoric acidWaste managementPhosphateEnvironmental scienceUranium oreChemistryEnvironmental engineeringEngineeringMetallurgyMaterials science

Abstract

fetched live from OpenAlex

Abstract Recovery of uranium from phosphoric acid on a commercial scale was first attempted in 1952 in the United States; at a plant operated by the Blockson Chemical Co. in Joilet, Ill, and used a chemical precipitation technique to recover the uranium as uranous phosphate. This plant was followed by two others, both in the United States. These plants started operating in 1955 and 1957, and both used octy-pyro-phsophoric acid as a solvent. While it was inexpensive, it had a short life and had to be replaced daily. All three uranium recovery plants were operated for several years until the price of uranium fell. With the large increase in the cost of energy in the mid-1970s, the price of uranium also rose. In the United States, where the indigenous phosphate rock contains relatively high uranium concentrations, the proposition of recovering it from phosphoric acid again became attractive; as a result 8 plants were built. (6 in Florida and 2 in Louisiana) Subsequently, plants were also built in Canada, Spain, Belgium, Israel, Iraq, Iran, and Taiwan. Again the price of uranium fell and most of the plants shut down quickly as they could not operate at a profit. However, at least 4 plants had long term contracts with United States utilities and were able to operate quite profitably for 10-15 years. During these years they were able to improve the process economics and efficiency. Operating costs of these plants were in the $11-13/pound range. Even though there may not have been any operating plants after 1997, research on the recovery of uranium from phosphoric acid did not stop. If any new plants are to be built, most likely they will be based on solvent extraction as this is the most proven and still the most economic process.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.002
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.085
Threshold uncertainty score0.285

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0020.002
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0040.002
Scholarly communication0.0050.006
Open science0.0010.002
Research integrity0.0030.004
Insufficient payload (model declined to judge)0.0850.053

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.222
Teacher spread0.214 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations13
Published2014
Admission routes1
Has abstractyes

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