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Record W2107522820 · doi:10.1002/pen.20622

Effect of organoclay content on the rheology, morphology, and physical properties of polyolefin elastomers and their blends with polypropylene

2006· article· en· W2107522820 on OpenAlexaff
Jeremy R. Austin, Marianna Kontopoulou

Bibliographic record

VenuePolymer Engineering and Science · 2006
Typearticle
Languageen
FieldMaterials Science
TopicPolymer Nanocomposites and Properties
Canadian institutionsQueen's University
Fundersnot available
KeywordsOrganoclayMaterials sciencePolyolefinElastomerPolypropyleneThermoplastic elastomerComposite materialNanocompositeEthylene propylene rubberRheologyVulcanizationMontmorillonitePolymer blendPolymerNatural rubberThermal stabilityCopolymerChemical engineering

Abstract

fetched live from OpenAlex

Abstract The effect of onium‐ion exchanged montmorillonite clay (organoclay) on the rheology and physical properties of maleated ethylene–octene copolymer and ethylene–propylene rubber elastomers has been examined. The formation of a nanocomposite hybrid, containing substantial amounts of exfoliated clay, was accompanied by significant increases in the complex viscosity, elastic and loss moduli, and a narrowing of the region of linear viscoelasticity, attributed to both filler/polymer and filler/filler interactions. The properties of blends of these elastomers with polypropylene were dominated by the reinforced elastomeric matrix, into which the organoclay resided preferentially. The nanocomposite blends exhibited very fine morphologies, as well as a good balance of stiffness and ductility and enhanced thermal stability. POLYM. ENG. SCI., 46:1491–1501, 2006. © 2006 Society of Plastics Engineers

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.181
Teacher spread0.174 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations75
Published2006
Admission routes1
Has abstractyes

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