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Record W2128323772 · doi:10.1021/jp071379f

X-ray Excited Optical Luminescence Studies of ZnO and Eu-Doped ZnO Nanostructures

2007· article· en· W2128323772 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueThe Journal of Physical Chemistry C · 2007
Typearticle
Languageen
FieldMaterials Science
TopicZnO doping and properties
Canadian institutionsCanadian Light Source (Canada)University of SaskatchewanWestern University
Fundersnot available
KeywordsPhotoluminescenceMaterials scienceLuminescenceDopantNanostructureNucleationDopingBand gapExcited stateXANESOptoelectronicsWurtzite crystal structureNanotechnologyZincChemistryAtomic physicsMetallurgy

Abstract

fetched live from OpenAlex

Pure (ZnO) and Eu-doped ZnO (Eu:ZnO) nanostructures have been grown in different morphologies by thermal evaporation. The growth of the structures depends on the temperature and concentration gradient during material deposition as well as on the doping species. X-ray excited optical luminescence (XEOL) from nanostructured ZnO and Eu:ZnO shows a correlation of optical properties with morphology on a nanoscale. In particular, the relative intensity of band gap and defect emission (green light) changes drastically in Eu:ZnO and ZnO nanostructures with different morphology. In this Article, we present experimental results from Eu:ZnO and ZnO nanostructures, using synchrotron radiation-based XEOL, time-gated XEOL, and element specific XANES with partial and total photoluminescence yield (PLY). Our results suggest that the rare earth dopant most likely affects the energy transfer and structural changes by nucleation, rather than direct radiative decay from Eu sites.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.260

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.022
GPT teacher head0.287
Teacher spread0.265 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it