<i>Florisphaera profunda</i> and the origin and diagenesis of carbonate phases in eastern Mediterranean sapropel units
Bibliographic record
Abstract
High relative concentrations of the lower photic zone nannofossil Florisphaera profunda have been reported in all recent eastern Mediterranean sapropels. In the most recent sapropel (S1), high bulk sediment Sr/Ca ratios occur along with high F. profunda contents toward the base of the unit, exemplified here in four cores from 1.5–3.5 km water depth. Co‐occurring biogenic carbonates contain insufficient Sr to account for these high Sr concentrations, and X‐ray diffraction and selective leaching show that the high Sr/Ca ratios are due to aragonite, the CaCO3 polymorph that is rarely preserved in deep marine sediments, with ∼1 wt % Sr. The possible sources of this aragonite include (1) precipitation with surface ocean production, (2) detrital input from shallow‐water sediments by high continental runoff, or (3) postdepositional diagenetic formation driven by increased pore water alkalinity resulting from sulphate reduction. The third formation mechanism for the aragonite is favored, in which case the similarity in the positions of the aragonite and F. profunda abundance maxima in sapropels is probably related to Corg accumulation and resulting sulphide diagenesis that produces high pore water alkalinity. There is clear micropaleontological evidence that dissolution of the less soluble biogenic low‐Mg CaCO3 is occurring, or has occurred, during early diagenesis in these sediments despite the coexistence of the more soluble high‐Mg calcite and aragonite polymorphs. Similar Sr/Ca maxima are also found associated with older sapropels, always located close both to local minima in surface ocean δ18O that signal maximum monsoon‐driven runoff and to maxima in diagenetic sediment sulphide contents. High freshwater flows from monsoons are believed to drive eastern Mediterranean sapropel formation through water column stabilization that favors F. profunda production and later through development of deep water column dysoxia/anoxia because of reduced ventilation. The relative abundances of F. profunda are high between 5 and 11 14C kyr B.P. with a maximum at ∼9 14C kyr B.P. The surface ocean production changes marked by F. profunda therefore begin earlier and finish later than the formation of the S1 sapropel, which only develops between 6 and 10 14C kyr B.P.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.001 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.001 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".