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Record W2169803336 · doi:10.1002/masy.200850406

Polypropylene Composites for Polymer Electrolyte Membrane Fuel Cell Bipolar Plates

2008· article· en· W2169803336 on OpenAlexaff
Rungsima Yeetsorn, Michael Fowler, Costas Tzoganakis, Wang Yuhua, M. R. Taylor

Bibliographic record

VenueMacromolecular Symposia · 2008
Typearticle
Languageen
FieldEngineering
TopicFuel Cells and Related Materials
Canadian institutionsUniversity of Waterloo
FundersU.S. Department of Energy
KeywordsMaterials scienceCarbon blackComposite materialPolypropyleneComposite numberGraphiteProton exchange membrane fuel cellElectrolyteConductive polymerElectrical conductorPolymerMembraneElectrodeChemistryNatural rubber

Abstract

fetched live from OpenAlex

Abstract The polymer electrolyte membrane fuel cell (PEMFC) holds tremendous promise for a variety of mobile and stationary power generation applications and is the cornerstone of the anticipated hydrogen economy. One of the major factors limiting fuel cell commercialization is the development of bipolar plates since bipolar plates account for approximately 70% of the PEMFC weight, and 60% of the stack manufacturing and materials cost. The objective of this research is to investigate a feasibility of a conductive composite family to be used as bipolar plates in a PEMFC, in order to get the highly conductive, light weight, and low cost bipolar plates. This work utilized a combination of a polypropylene and low cost conductive filler materials: graphite, conductive carbon black, and carbon fibers. The components were combined in a batch mixer and injection molded into samples for testing with loadings up to 65%wt of fillers. The novel blends were tested for electrical conductivity, hydrophobicity, rheology, and actual plates (16 cm2) were tested in fuel cell testing trials. The impact of different types of fillers on the composite properties was evaluated, as well as the synergetic effect of mixtures of fill types within a polypropylene matrix. From the results, the highest conductivity, 1900 S/m (in‐plane) and 156 S/m (through plane), was obtained with the 65% composite. Moreover, the effects of additives such as coupling agents, and intrinsically conductive polymer (polypyrrole) were observed in this work. The electrical conductivity was influenced by polypyrrole added to the polypropylene composite.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.169
Teacher spread0.165 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations24
Published2008
Admission routes1
Has abstractyes

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