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Record W2317446046 · doi:10.1021/je400014e

Dielectric Properties of Concentration-Dependent Ethanol + Acids Solutions at Different Temperatures

2013· article· en· W2317446046 on OpenAlexaff
Winny Routray, Valérie Orsat

Bibliographic record

VenueJournal of Chemical & Engineering Data · 2013
Typearticle
Languageen
FieldChemistry
TopicMicrowave-Assisted Synthesis and Applications
Canadian institutionsMcGill University
Fundersnot available
KeywordsEthanolAcetic acidPenetration (warfare)DielectricChemistryPenetration depthMicrowaveAnalytical Chemistry (journal)Dissipation factorMicrowave heatingMaterials scienceChromatographyOrganic chemistryOptics

Abstract

fetched live from OpenAlex

Dielectric properties of ethanol + HCl and ethanol + acetic acid heated at different temperature levels were recorded at microwave frequencies ranging from 0.5 GHz to 6 GHz, and the corresponding dissipation factor and depth of penetration of the solutions were calculated and analyzed using response surface methodology for the factors of temperature level and ethanol and acid (HCl and acetic acid) concentration generated using a central composite design. In case of mixtures with acetic acid, ethanol concentration and temperature were found to be the significant factors; however in the case of mixtures with HCl, HCl concentration was also found to be a significant factor contributing to all analyzed responses. The heating rate was interpreted in terms of the different factors based on their effects on dissipation factor and depth of penetration. Overall, with an increase in the concentration of ethanol and at lower temperature levels, the microwave heating rate was interpreted to be highest at 2.45 GHz. Among the acids, HCl was the only contributing factor and was interpreted to positively affect the heating rate; that is, with an increase in HCl concentration, the heating rate was observed to increase at 2.45 GHz.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.028
GPT teacher head0.220
Teacher spread0.193 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations13
Published2013
Admission routes1
Has abstractyes

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