Rational Synthesis of Metal–Organic Framework Nanocubes and Nanosheets Using Selective Modulators and Their Morphology-Dependent Gas-Sorption Properties
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
Nanocubes and nanosheets of [Cu 2 (ndc) 2 (dabco)] n metal–organic framework (ndc = 1,4-naphthalene dicarboxylate; dabco = 1,4-diazabicyclo[2.2.2]octane) were synthesized by using simultaneously acetic acid and pyridine or only pyridine, respectively, as selective modulators. This approach can tailor crystal growing on different directions for the size- and shape-controlled synthesis of metal–organic framework (MOF) nanocrystals whose structure is composed of two or more types of linkers using selective modulators. These MOF nanocrystals exhibit high crystallinity and higher CO 2 uptakes compared to that of the bulk MOF material or of the [Cu 2 (ndc) 2 (dabco)] n nanorods generated by using only acetic acid as the selective modulator, which may be due to the morphology effect on their gas sorption properties.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it