Simple, Chemoselective, Catalytic Olefin Isomerization
Why is this work in the frame?
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
No Canadian affiliation. An affiliation-only frame — the usual design — would never have seen this work. It is one of the works that make the case for inverting the frame.
Machine scores (provisional)
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
- Teacher spread
- 0.253 · how far apart the two teachers sit on this one work
- Validation status
score_only:v0-immature-baseline· verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it
Abstract
Catalytic amounts of Co(Sal(tBu,tBu))Cl and organosilane irreversibly isomerize terminal alkenes by one position. The same catalysts effect cycloisomerization of dienes and retrocycloisomerization of strained rings. Strong Lewis bases like amines and imidazoles, and labile functionalities like epoxides, are tolerated.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
The record
- Venue
- Journal of the American Chemical Society
- Topic
- Synthetic Organic Chemistry Methods
- Field
- Chemistry
- Canadian institutions
- —
- Funders
- National Institute of General Medical SciencesBaxter International FoundationNational Institutes of HealthAmgenFonds de recherche du Québec – Nature et technologiesAlfred P. Sloan FoundationEli Lilly and CompanyBoehringer Ingelheim
- Keywords
- ChemistryIsomerizationOlefin fiberCatalysisSimple (philosophy)Organic chemistryCombinatorial chemistry
- Has abstract in OpenAlex
- yes