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Record W2328794584 · doi:10.1021/ie2008357

Mass Transfer Performance of CO<sub>2</sub> Absorption into Aqueous Solutions of 4-Diethylamino-2-butanol, Monoethanolamine, and <i>N</i>-Methyldiethanolamine

2012· article· en· W2328794584 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2012
Typearticle
Languageen
FieldEngineering
TopicCarbon Dioxide Capture Technologies
Canadian institutionsUniversity of Regina
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsMass transferMass transfer coefficientStructured packingChemistryAbsorption (acoustics)Aqueous solutionAnalytical Chemistry (journal)Volumetric flow rate2-ButanolButanolPacked bedChromatographyMaterials scienceThermodynamicsOrganic chemistryEthanol

Abstract

fetched live from OpenAlex

The mass transfer performance of the absorption of CO 2 in an aqueous solution of monoethanolamine was evaluated experimentally in a lab-scale absorber packed with high efficiency DX structured packing and compared with that of methyldiethanolamine (MDEA) as well as that of a newly developed tertiary amino alcohol, 4-diethylamino-2-butanol (DEAB). The absorption experiments were conducted at atmospheric pressure, using a feed gas mixture containing 14.9% CO 2 and 85.1% nitrogen in an absorption column containing DX structured packing. The absorption performance was presented in terms of the CO 2 removal efficiency, absorber height requirement, effective interfacial area for mass transfer, and overall mass-transfer coefficient ( K G a v ). In particular, the effects of parameters such as inert gas flow rate and liquid flow rate were compared for both DEAB and MDEA. The results show that the DEAB has a much higher removal efficiency for CO 2 along the height of the column than MDEA. Also, the K G a v of DEAB was much higher than that for MDEA. For all the solvents, the K G a v increased as the liquid flow rate was increased. An empirical correlation for the mass transfer coefficient for the CO 2 -DEAB system has been developed as a function of the process parameters. In terms of comparison, the results show that the DEAB system provided an excellent overall mass transfer coefficient, which is higher than that of the MDEA system but less than that of MEA.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.043
GPT teacher head0.262
Teacher spread0.219 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it