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Record W2398495679 · doi:10.1021/acssuschemeng.6b00321

Perspective on Polylactic Acid (PLA) based Sustainable Materials for Durable Applications: Focus on Toughness and Heat Resistance

2016· article· en· W2398495679 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueACS Sustainable Chemistry & Engineering · 2016
Typearticle
Languageen
FieldMaterials Science
Topicbiodegradable polymer synthesis and properties
Canadian institutionsUniversity of Guelph
FundersOntario Ministry of Economic Development and InnovationNatural Sciences and Engineering Research Council of CanadaOntario Ministry of Agriculture, Food and Rural AffairsGovernment of Canada
KeywordsBioplasticToughnessPolylactic acidMaterials scienceImpact resistanceEnvironmentally friendlyComposite materialPolymerEngineeringWaste managementEcology

Abstract

fetched live from OpenAlex

Evolution of the bioplastics industry has changed directions dramatically since the early 1990s. The latest generation is moving toward durable bioplastics having high biobased content. The main objective is to replace "fossil carbon" with "renewable carbon", a holistic strategy to mitigate climate change by minimizing the environmental impact of a product throughout its life cycle. Durable bioplastics is desired for multiuse long-term application in automotive, electronics and other industries. One necessary requirement for them is to be both tough and strong, yet the two attributes are often mutually exclusive. Does this mean a biobased and biodegradable polymer as polylactic acid (PLA) with its high strength but low toughness cannot be adopted for durable applications? Well, not exactly; this is where the concept of tailoring the properties of PLA to achieve stiffness–toughness balance along with acceptable heat resistance comes into play. In this perspective, we summarize the recent research progress in addressing the toughness vs strength and heat resistance conflict inherent in PLA. Blends having super toughness and composites based on the toughened PLA blends formulated to obtain desired material properties are covered. Morphology and crystallinity that individually contribute to toughness and heat resistance have also been elucidated.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.066
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.207
Teacher spread0.201 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it