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Record W2490318446 · doi:10.1520/mnl11424m

Chapter 4: Simulated Distillation Measurement

2008· book-chapter· en· W2490318446 on OpenAlexaff
D. Susan Workman

Bibliographic record

Venuenot available
Typebook-chapter
Languageen
FieldEngineering
TopicProcess Optimization and Integration
Canadian institutionsImperial Oil (Canada)
Fundersnot available
KeywordsDistillationEnvironmental scienceProcess engineeringComputer scienceChromatographyEngineeringChemistry

Abstract

fetched live from OpenAlex

DISTILLATION IS THE MOST WIDELY USED SEPARAtion process in the petroleum industry. Knowledge of the boiling range of crude oils, refined fractions, and finished products has been an essential part of quality determination since the beginning of the refining industry. Routine laboratory scale physical distillation tests have been extensively used for determining the boiling ranges of crude feedstocks, distillation fractions, and a complete slate of refinery products (ASTM methods D86, D1160, D2892, and D5236) [1–4]. An alternative to physical distillation or true boiling point distillation is simulated distillation by gas chromatography. Eggerston et al. first described simulated distillation in 1960 [5]. Simulated distillation (SD) is equivalent to a 100 theoretical-plate physical distillation, is very rapid, reproducible, and easily automated, requires only a small microlitre sample volume, and can better define initial and final boiling points. Boiling range distribution data are used to evaluate new crude oils, to confirm crude quality, to monitor crude quality during transportation, and to provide information for the optimization of refinery processes. The ability to quickly and reliably evaluate crude oils and fractions has important economic implications. The full development of simulated distillation methods as routine procedures has had a significant impact on the ability to determine boiling point information for crude oils and petroleum products.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.030
Threshold uncertainty score0.100

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0020.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0300.020

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.031
GPT teacher head0.189
Teacher spread0.158 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2008
Admission routes1
Has abstractyes

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