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Record W2565007042 · doi:10.1021/acs.estlett.6b00452

Atmospheric Mercury Temporal Trends in the Northeastern United States from 1992 to 2014: Are Measured Concentrations Responding to Decreasing Regional Emissions?

2016· article· en· W2565007042 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

aboutThe title or abstract carries a Canadian signal from the geographic lexicon.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueEnvironmental Science & Technology Letters · 2016
Typearticle
Languageen
FieldEnvironmental Science
TopicMercury impact and mitigation studies
Canadian institutionsnot available
FundersNew York State Energy Research and Development AuthorityNational Oceanic and Atmospheric AdministrationU.S. Environmental Protection AgencyNational Science Foundation
KeywordsMercury (programming language)Environmental scienceAtmospheric sciencesElemental mercuryEnvironmental chemistryChemistryGeology

Abstract

fetched live from OpenAlex

Long-term atmospheric mercury measurements at Underhill, VT (VT99), and Huntington Forest, NY (NY20), from 1992 to 2014 and 2005 to 2014, respectively, were used to determine concentration trends using Mann–Kendall’s tau test with Sen’s slope estimator. These data, measured generally downwind of large Hg sources in the Midwestern United States, provide the longest record of ambient Hg concentrations available in the United States. At VT99, concentrations of gaseous element mercury (GEM), gaseous oxidized mercury (GOM), and particle-bound mercury (PBM) declined at rates of −1.8, −3.2, and −6.7%/year, respectively. At NY20, GEM and GOM concentrations declined at rates of −1.6 and −7.8%/year, respectively; however, PBM concentrations increased at a rate of 2.0%/year, which is likely related to winter wood burning. A trajectory ensemble analysis using the potential source contribution function indicates the source locations associated with high mercury concentrations changed from Toronto–Buffalo and Pennsylvania areas to east coast urban centers. The declining GEM concentrations in the northeastern United States are positively correlated with decreasing SO 2 emissions in the upwind area. Overall, the results indicate that decreased mercury concentrations measured during the past decade are consistent with decreased Hg emissions from regional point sources and that increasing global emissions have not overwhelmed those decreases.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.398
Threshold uncertainty score0.802

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.003
Science and technology studies0.0010.002
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.253
Teacher spread0.236 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it