Catalytic Zirconium/Hafnium-Based Metal–Organic Frameworks
Why is this work in the frame?
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
No Canadian affiliation. An affiliation-only frame — the usual design — would never have seen this work. It is one of the works that make the case for inverting the frame.
Machine scores (provisional)
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
- Teacher spread
- 0.220 · how far apart the two teachers sit on this one work
- Validation status
score_only:v0-immature-baseline· verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it
Abstract
Metal–organic frameworks (MOFs) are highly versatile materials that find applications in several fields. Highly stable zirconium/hafnium-based MOFs were recently introduced and nowadays represent a rapidly growing family. Their unique and intriguing properties make them privileged materials and outstanding candidates in heterogeneous catalysis, finding use either as catalysts or catalyst supports. Various techniques have been developed to incorporate active species into Zr-MOFs, giving rise to catalysts that often demonstrate higher performances or unusual activity when compared with their homogeneous analogues. Catalytic functions are commonly incorporated at the zirconium-oxide node, at the linker, or encapsulated in the pores. Representative examples are discussed, and advantages in adopting Zr- and Hf-MOFs in catalytic applications are highlighted.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
The record
- Venue
- ACS Catalysis
- Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Field
- Chemistry
- Canadian institutions
- —
- Funders
- Army Research OfficeBasic Energy SciencesNatural Sciences and Engineering Research Council of CanadaDivision of Materials ResearchOffice of ScienceNorthwestern UniversityDefense Threat Reduction AgencyNational Defense Science and Engineering GraduateSchweizerischer Nationalfonds zur Förderung der Wissenschaftlichen ForschungU.S. Department of DefenseU.S. Department of EnergyNational Science Foundation
- Keywords
- ZirconiumCatalysisHafniumMetal-organic frameworkMaterials scienceHomogeneousLinkerNanotechnologyCombinatorial chemistryChemistryComputer scienceOrganic chemistryMetallurgy
- Has abstract in OpenAlex
- yes