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Preparation of poly(methyl methacrylate)‐Silica nanoparticles via differential microemulsion polymerization and physical properties of <scp>NR</scp>/<scp>PMMA</scp>‐<scp>S</scp>i<scp>O</scp><sub>2</sub> hybrid membranes

2017· article· en· 17 citations· W2617743101 on OpenAlex· 10.1002/pen.24611

Why is this work in the frame?

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

Canadian affiliationAn author listed a Canadian institution. This is the only route the usual frame has.
Canadian funderA Canadian agency funded it. The work may carry no Canadian affiliation at all.

The three-model screen

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All three models called this out of scope.

stratum: aff_core · design weight: 5595.24 (the sample is stratified; any rate computed without the weight is wrong)
Claude Opus 4.8OUT
genre: empirical
about Canada: no
confidence: high

Polymer science on PMMA-silica nanoparticles and hybrid membranes; the object is a material.

GPT-5.6 (high)OUT
genre: empirical
about Canada: no
confidence: high

The study investigates polymer nanoparticles and membrane properties, not research practice.

Grok 4.5OUT
genre: empirical
about Canada: no
confidence: high

Materials science study of PMMA-silica nanoparticles and membranes; not about research itself.

Abstract

Poly(methy methacrylate) (PMMA)‐SiO 2 nanoparticles were prepared via differential microemulsion polymerization. The effects of silica loading, surfactant concentration, and initiator concentration on monomer conversion, particle size, particle size distribution, grafting efficiency, and silica encapsulation efficiency were investigated. A high monomer conversion of 99.9% and PMMA‐SiO 2 nanoparticles with a size range of 30 to 50 nm were obtained at a low surfactant concentration of 5.34 wt% based on monomer. PMMA‐SiO 2 nanoparticles showed spherical particles with a core‐shell morphology by TEM micrographs. A nanocomposite membrane from natural rubber (NR) and PMMA‐SiO 2 emulsion was studied for mechanical and thermal properties and pervaporation of water‐ethanol mixtures. PMMA‐SiO 2 nanoparticles which were uniformly dispersed in NR matrix, significantly enhanced mechanical properties and showed high water selectivity in permeate flux. Thus, the NR/PMMA‐SiO 2 hybrid membranes have great potential for pervaporation process in membrane applications. POLYM. ENG. SCI., 2017. © 2017 Society of Plastics Engineers

Stored with the screening record, where it is evidence for the labels above.

The record

Venue
Polymer Engineering and Science
Topic
Membrane Separation and Gas Transport
Field
Engineering
Canadian institutions
University of Waterloo
Funders
Natural Sciences and Engineering Research Council of Canada
Keywords
Materials sciencePervaporationChemical engineeringMonomerNanoparticleMethyl methacrylateEmulsion polymerizationMicroemulsionMembranePolymerizationPolymer chemistryParticle sizeNanocompositePermeationPulmonary surfactantPolymerComposite materialNanotechnologyChemistry
Has abstract in OpenAlex
yes