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Record W2809346853 · doi:10.1039/c7cs00701a

Harnessing the properties of colloidal quantum dots in luminescent solar concentrators

2018· review· en· W2809346853 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueChemical Society Reviews · 2018
Typereview
Languageen
FieldMaterials Science
TopicQuantum Dots Synthesis And Properties
Canadian institutionsInstitut National de la Recherche Scientifique
FundersNatural Sciences and Engineering Research Council of CanadaNatural Science Foundation of Shandong Province
KeywordsLuminescenceQuantum dotColloidNanotechnologyMaterials scienceOptoelectronicsAstrobiologyEngineering physicsPhysicsChemistryPhysical chemistry

Abstract

fetched live from OpenAlex

Luminescent solar concentrators (LSCs) can serve as large-area sunlight collectors, are suitable for applications in high-efficiency and cost-effective photovoltaics (PVs), and provide adaptability to the needs of architects for building-integrated PVs, which makes them an attractive option for transforming buildings into transparent or non-transparent electricity generators. Compared with traditional organic dyes, colloidal semiconducting quantum dots (QDs) are excellent candidates as emitters for LSCs because they exhibit wide size/shape/composition-tunable absorption spectra ranging from ultraviolet to near infrared, significantly overlapping with the solar spectrum. They also feature narrow emission spectra, high photoluminescence quantum yields, high absorption coefficients, solution processability and good photostability. Most importantly, QDs can be engineered to provide a minimal overlap between absorption and emission spectra, which is key to the realization of large-area LSCs with largely suppressed reabsorption energy losses. In this review article, we will first present and discuss the working principle of LSCs, the synthesis of colloidal QDs using wet-chemistry approaches, the optical properties of QDs, their band alignment and the intrinsic relationship between the band energy structure and optical properties of QDs. We focus on emerging architectures, such as core/shell QDs. We then highlight recent progress in QD-based LSCs and their anticipated applications. We conclude this review article with the major challenges and perspectives of LSCs in future commercial technologies.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.870
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0030.001
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.101
GPT teacher head0.307
Teacher spread0.206 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it