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Record W2914722823 · doi:10.1002/aic.16573

Theory of dissolution and precipitation waves—redux

2019· article· en· W2914722823 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

fundA Canadian funder is recorded on the work.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueAIChE Journal · 2019
Typearticle
Languageen
FieldComputer Science
TopicAdvanced Mathematical Modeling in Engineering
Canadian institutionsnot available
FundersEnergi Simulation
KeywordsDissolutionPartial differential equationSaturation (graph theory)IonDispersion (optics)PrecipitationThermodynamicsConservation lawChemistryMathematicsMathematical analysisMechanicsPhysicsPhysical chemistryMeteorology

Abstract

fetched live from OpenAlex

Abstract We present a local equilibrium theory for the reactive transport of two salts that share an anion in an ideal solution. We revisit this classic problem using the theory of hyperbolic partial differential equations accounting for the volume of precipitates. We construct analytical solutions for the 2 × 2 system of conservation laws in the absence of hydrodynamic dispersion. The character of the system depends on the saturation of the salts, that is, whether the fluid is saturated with both, either of the two or none of the salts. We provide a comprehensive analysis of the system and its solution. Each primitive variable, the amount of precipitate and the concentration of ions, remains constant along one class of waves that propagate in the system. The analysis of the system allows identification of seven bifurcations with respect to the intermediate state.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Theoretical or conceptual · Consensus signal: none
GenreCandidate signal: Methods · Consensus signal: none
Teacher disagreement score0.635
Threshold uncertainty score0.146

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.244
Teacher spread0.232 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it