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Record W2954836007 · doi:10.1002/admi.201900552

Nanocomposite of Nitrogen‐Doped Graphene/Polyaniline for Enhanced Ammonia Gas Detection

2019· article· en· W2954836007 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueAdvanced Materials Interfaces · 2019
Typearticle
Languageen
FieldEngineering
TopicGas Sensing Nanomaterials and Sensors
Canadian institutionsOkanagan University CollegeUniversity of British Columbia, Okanagan CampusUniversity of British ColumbiaUniversity of Toronto
FundersNatural Sciences and Engineering Research Council of CanadaUniversity of Toronto
KeywordsGrapheneNanocompositeMaterials sciencePolyanilineTrimethylamineDimethylamineNanotechnologyChemical engineeringChemiresistorOxideDopingComposite materialPolymerPolymerizationOrganic chemistryOptoelectronicsChemistry

Abstract

fetched live from OpenAlex

Abstract Graphene nanosheets are widely used for designing functional nanocomposite sensors that are highly sensitive. In this study, nitrogen‐doped reduced graphene oxide (N‐rGO) polyaniline (PANI) nanocomposites composed of localized heterojunctions are prepared for the detection of ammonia, dimethylamine, and trimethylamine gases with superior sensing performances. rGO nanosheets with electrical properties modified via N‐doping are strategically incorporated in p‐type PANI via in situ synthesis, with the nanosheets acting as templates for PANI growth. N‐rGO nanosheets featuring large specific area, high electrical conductivity, and n‐type semiconductive behavior combined with the attractive electrical p‐type characteristics of PANI are found to be highly beneficial for improving detection sensitivity toward ammonia, dimethylamine, and trimethylamine gases at 25 °C. Overall, the detection sensitivity of the advanced N‐rGO nanocomposites is more than two times higher than that of PANI alone. Moreover, the N‐rGO/PANI nanocomposites reach an estimated limit of detection for ammonia gas down to the sub‐ppm range. Improvement in sensing performance is also observed for rGO/PANI and GO/PANI nanocomposites; however, the level of the improvement is less than that of N‐rGO/PANI nanocomposites. This study demonstrates the excellent potential of designing advanced graphene nanocomposite gas sensors with superior performances by manipulating the electronic properties of the graphene nanosheets.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.208
Teacher spread0.203 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it