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Record W2980183057 · doi:10.1002/cjce.23667

Copper recovery from nickel laterite with high‐iron content: A continuous process from mining waste

2019· article· en· W2980183057 on OpenAlexvenueno aff
Isadora Dias Perez, Amilton Barbosa Botelho, Paula Aliprandini, Denise Crocce Romano Espinosa

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2019
Typearticle
Languageen
FieldEngineering
TopicExtraction and Separation Processes
Canadian institutionsnot available
FundersFundação de Amparo à Pesquisa do Estado de São Paulo
KeywordsCopperLateriteElutionNickelPrecipitationChemistryImpurityIon exchangeChelationChelating resinMetallurgyMaterials scienceInorganic chemistryChromatographyMetalIonMetal ions in aqueous solution

Abstract

fetched live from OpenAlex

Abstract The waste product from the hydrometallurgical processing of nickel laterite ores can contain valuable metals, making their recovery economically viable. However, the high‐impurities content, mainly iron, makes the process technically unfeasible. As a result, the separation of metals from the leach solution must be selective. Among the techniques available, the use of chelating resin is advantageous due to its selectivity and low energy consumption. Among the commercial chelating resins available, Dowex XUS 43605 has been shown to be highly selective for copper and can be used with a high impurities content. Although there are studies on the use of Dowex XUS 43605, none have evaluated a high impurities content and modelled a continuous process. For this reason, the aim of this work was to investigate copper recovery by a continuous process. The Dowex XUS 43605 chelating resin with HPPA functional group was used in ion‐exchange experiments. Column experiments were performed in two steps: loading (to recover copper) and elution (to obtain a copper‐rich solution). The removal of iron and the subsequent collection of copper were possible in a precipitation step using CaCO3. The results showed that the solution obtained from elution had a copper concentration that was 10 times higher than in the loading. All of the iron was removed from the elution solution at pH 3.5 with 5% of copper losses. Copper precipitation was possible at pH 5.5. From the results obtained, a proposed flowsheet for recovering copper was suggested.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0000.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.175
Teacher spread0.167 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations35
Published2019
Admission routes1
Has abstractyes

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