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Record W2990508618 · doi:10.82308/38054

Experimental study of bubble growth in Stromboli basalt melts at 1 atmosphere

2007· article· en· W2990508618 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

fundA Canadian funder is recorded on the work.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueeScholarship@McGill (McGill) · 2007
Typearticle
Languageen
FieldChemistry
TopicPigment Synthesis and Properties
Canadian institutionsnot available
FundersArgonne National LaboratoryBasic Energy SciencesMcGill UniversityU.S. Department of EnergyOffice of ScienceNational Science Foundation
KeywordsBubbleCoalescence (physics)NucleationMaterials scienceMineralogyAnalytical Chemistry (journal)ChemistryThermodynamicsMechanicsChromatographyPhysics

Abstract

fetched live from OpenAlex

In order to investigate bubble formation and growth at 1 atmosphere, degassing experiments using a Stromboli basalt with dissolved H2O or H2O + CO2 were performed in a custom furnace on a beamline at the Advanced Photon Source. The glasses were synthesized at 1250°C and 1000 MPa, with ~3.0 wt%, ~5.0 wt%, or ~7.0 wt% H2O or with mixtures of H2O + CO2, ~3.0 wt% H2O and ~440 ppm CO2, ~5.0 wt% H2O and 880 ppm CO2, ~7.0 wt% H2O and ~1480 ppm CO2, then heated on the beamline while recording the bubble growth. The 3D bubble size distributions in the quenched samples were then studied with synchrotron X-ray microtomography. The experimental results show that bubble nucleation and growth are volatile-concentration dependent. Bubbles can easily nucleate in melts initially containing high volatile concentrations. CO2 has no significant effect on bubble formation and growth because of low CO2 concentrations. Multiple nucleation events occur in most of these degassing samples, and they are more pronounced in more supersaturated melts. Bubble growth is initially controlled by viscosity near glass transition temperatures and by diffusion at higher temperatures where melt viscous relaxation occurs rapidly. Bubble foam forms when bubbles are highly connected due to coalescence, and bubbles begin pop, 10 to 20 seconds after the foam is developed. The degree of bubble coalescence increases with time, and bubble coalescence can significantly change the bubble size distribution. Bubble size distributions follow power-law relations at vesicularities of 1.0% to 65%, and bubble size distributions evolve from power-law relations to exponential relations at vesicularities of 65% to 83%. This evolution is associated with the change from far-from-equilibrium degassing to near-equilibrium degassing. The experimental results imply that during basaltic eruptions both far-from-equilibrium degassing and near-equilibrium degassing can occur. The far-from-equilibrium degassing generally generates the power-law bubble size distributions whereas the near-equilibrium degassing produces exponential bubble size distributions Bubbles begin to pop when the vesicularities attain 65% to 83%. Bubble expansion in the foam possibly accounts for the mechanism of magma fragmentation.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.084
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.022
GPT teacher head0.240
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it