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Record W3082501769 · doi:10.1111/wej.12634

Improved biodegradation of pharmaceuticals after mild photocatalytic pretreatment

2020· article· en· W3082501769 on OpenAlexaff
Arnoud de Wilt, Maricor J. Arlos, Mark R. Servos, H.H.M. Rijnaarts, Alette Langenhoff, Wayne J. Parker

Bibliographic record

VenueWater and Environment Journal · 2020
Typearticle
Languageen
FieldEnvironmental Science
TopicPharmaceutical and Antibiotic Environmental Impacts
Canadian institutionsUniversity of Waterloo
Fundersnot available
KeywordsPhotocatalysisBiodegradationChemistryNaproxenDiclofenacEnvironmental chemistryOrganic chemistryMedicineCatalysis

Abstract

fetched live from OpenAlex

Abstract The combination of photocatalysis and biodegradation was investigated for the removal of nine selected pharmaceuticals as a means to reduce loadings into the environment. The combined process, consisting of a resource‐efficient mild photocatalysis and a subsequent biological treatment, was compared to single processes of intensive photocatalysis and biological treatment. The UV‐TiO 2 based photocatalysis effectively removed atorvastatin, atenolol and fluoxetine (>80%). Biological treatment after mild photocatalytic pretreatment removed diclofenac effectively (>99%), while it persisted during the single biological treatment (<50%). Moreover, the biodegradation of atorvastatin, caffeine, gemfibrozil and ibuprofen was enhanced after mild photocatalytic pretreatment compared to biological treatment alone. The enhanced biodegradation of these pharmaceuticals appeared to be triggered by the biodegradation of photocatalytic products. Mild photocatalysis followed by biological treatment is an effective and resource‐efficient combination for pharmaceutical removal that could substantially reduce the loading of pharmaceuticals into the environment.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.005

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.029
GPT teacher head0.259
Teacher spread0.230 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations11
Published2020
Admission routes1
Has abstractyes

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